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Metal Residues in Semiconducting Polymers: Impact on the Performance of Organic Electronic Devices

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorUSLUER, Özlem
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorABBAS, Mamatimin
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorWANTZ, Guillaume
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorVIGNAU, L.
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorHIRSCH, Lionel
IDREF: 111272459
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorGRANA, Eftychia
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorBROCHON, Cyril
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorCLOUTET, Eric
IDREF: 151048681
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
hal.structure.identifierTeam 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies
dc.contributor.authorHADZIIOANNOU, Georges
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2014
dc.identifier.issn2161-1653
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19617
dc.description.abstractEnThe effect of impurities on the optoelectronic and charge transport properties of semi-conducting polymers was investigated through the performance of organic photovoltaics (OPVs) and organic field effect transistors (OFETs), respectively. A model representative semi-conducting polymer, i.e. poly(3-hexylthiophene) (P3HT), was synthesized and purified using different methods such as precipitation, metals' complexation, and Soxhlet extraction. After the purification processes, each fraction was analyzed to determine its composition in metals (impurities) by various techniques. OFETs and OPVs fabricated from these purified polymer fractions were found to show different charge carrier properties and photovoltaic behaviors. The purest fraction which was obtained after soxhlet extraction complemented by metals' complexation with the help of eth-ylenediamine and 15-crown-5 ether showed the best performance in both OPVs and OFETs.
dc.language.isoen
dc.publisherWashington, D.C : American Chemical Society
dc.subject.enPoly(3-hexylthiophene)
dc.subject.enmetal residues
dc.subject.enpurification
dc.subject.enorganic field-effect transistor
dc.subject.enorganic solar cell
dc.title.enMetal Residues in Semiconducting Polymers: Impact on the Performance of Organic Electronic Devices
dc.typeArticle de revue
dc.identifier.doi10.1021/mz500590d
dc.subject.halChimie/Polymères
bordeaux.journalACS Macro Letters
bordeaux.page1134-1138
bordeaux.volume3
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue11
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-02922703
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02922703v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ACS%20Macro%20Letters&rft.date=2014&rft.volume=3&rft.issue=11&rft.spage=1134-1138&rft.epage=1134-1138&rft.eissn=2161-1653&rft.issn=2161-1653&rft.au=USLUER,%20%C3%96zlem&ABBAS,%20Mamatimin&WANTZ,%20Guillaume&VIGNAU,%20L.&HIRSCH,%20Lionel&rft.genre=article


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