Synthesis and blue luminescence of a soluble newly designed carbazole main-chain polymer
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des Polymères Organiques [LCPO] | |
| dc.contributor.author | CLOUTET, Eric
IDREF: 151048681 | |
| dc.contributor.author | OLIVERO, C. | |
| dc.contributor.author | ADÈS, D. | |
| dc.contributor.author | CASTEX, M.-C. | |
| dc.contributor.author | SIOVE, A. | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2002 | |
| dc.identifier.issn | 0032-3861 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19592 | |
| dc.description.abstractEn | A new electroactive polymer with alternating conjugated–nonconjugated repeating units in the main chain was synthesized by step growth polymerization of α,ω-bis(N-carbazolyl)octane in chloroform solution with excess of iron trichloride, and in the presence of N-ethylcarbazole as a terminating agent. The resulting α,ω-N-ethylcarbazole terminated poly(3,3′-bicarbazyl-N,N′-octylene)s are readily soluble in common organic solvents and have good film-forming capabilities, partly because of the special design of the polymer backbone constituted by stiff bicarbazyl chromophores linked by flexible eight-carbon segments. Soluble materials with molecular weights up to 105 g/mol and polydispersity indices around 3.3 were obtained. Purified samples exhibiting quite low polydispersity indices (in the range 1.5–1.7) can be prepared by a selective fractionation of the crude polymer from benzene/methanol mixtures. Structural analysis of these new ‘stairs-like’ polymers disclosed their well-defined character with an aromatic linkage exclusively at position 3 on the carbazole moieties. Electrochemical studies of polymer films exhibited two reversible redox processes between 0 and 1.5 V vs saturated calomel electrode. The photoluminescence (PL) of the polymer in solution and as cast films revealed an intense blue emission and the same intensity level than that of the N,N′-diethyl-3,3′-bicarbazyl molecule, taken as a model of the aromatic segment of the repeating unit. Such a processable and purifiable polymer with bicarbazyl-isolated fluorophores is quite promising for the fabrication of efficient blue light-emitting devices. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.title.en | Synthesis and blue luminescence of a soluble newly designed carbazole main-chain polymer | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/S0032-3861(02)00080-0 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Polymer | |
| bordeaux.page | 3489-3495 | |
| bordeaux.volume | 43 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 12 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-02930287 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-02930287v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer&rft.date=2002&rft.volume=43&rft.issue=12&rft.spage=3489-3495&rft.epage=3489-3495&rft.eissn=0032-3861&rft.issn=0032-3861&rft.au=CLOUTET,%20Eric&OLIVERO,%20C.&AD%C3%88S,%20D.&CASTEX,%20M.-C.&SIOVE,%20A.&rft.genre=article |
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