Facile synthesis of 1,4-cis-polyisoprene–polypeptide hybrids with different architectures
| dc.rights.license | open | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | RADCHENKO, Alexei | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | GRANGE, Jérémie | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | VAX, Amelie | |
| hal.structure.identifier | Société Michelin | |
| dc.contributor.author | JEAN-BAPTISTE-DIT-DOMINIQUE, François | |
| hal.structure.identifier | Société Michelin | |
| dc.contributor.author | MATMOUR, Rachid | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | GRELIER, Stéphane | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | PERUCH, Frédéric
IDREF: 152900748 | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2019 | |
| dc.identifier.issn | 1759-9954 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/19572 | |
| dc.description.abstractEn | The synthesis of polypeptide hybrids by controlled/living ring-opening polymerization of N-carboxyanhydrides (NCA) using Schreiner′s thiourea catalyst and amino-alcohol terminated poly(1,4-cis-isoprene)s as initiators was demonstrated for γ-benzyl-ʟ-glutamate (BLG) and ε-tert-butyloxycarbonyl-ʟ-lysine (BLL) NCAs. One-pot synthesis of amino-alcohol terminated macroinitiators from heterotelechelic keto/aldehyde polyisoprene by reductive amination of carbonyl(s) was presented. Selection of amines allowed to obtain mono-, di-and tri-functional macroinitiators that were used for the synthesis of polyisoprene-polypeptide hybrids of different architecture: AB, BAB, AB2, BAB2, CBABC. Due to the living character of the polymerization, the molar mass of the polypeptide blocks could be controlled by the monomer to initiator ratio (6000<Mn<44000 g/mol), while sequential monomer addition allowed the synthesis of a pentablock terpolymer: poly(BLG-b-BLL-b-isoprene-b-BLL-b-BLG) | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry - RSC | |
| dc.title.en | Facile synthesis of 1,4-cis-polyisoprene–polypeptide hybrids with different architectures | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c9py00241c | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Polymer Chemistry | |
| bordeaux.page | 2456-2468 | |
| bordeaux.volume | 10 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 19 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-02136046 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-02136046v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer%20Chemistry&rft.date=2019&rft.volume=10&rft.issue=19&rft.spage=2456-2468&rft.epage=2456-2468&rft.eissn=1759-9954&rft.issn=1759-9954&rft.au=RADCHENKO,%20Alexei&GRANGE,%20J%C3%A9r%C3%A9mie&VAX,%20Amelie&JEAN-BAPTISTE-DIT-DOMINIQUE,%20Fran%C3%A7ois&MATMOUR,%20Rachid&rft.genre=article |
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