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Polymers with novel topologies by ring-opening metathesis polymerization of macromonomers

dc.rights.licenseopen
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorGRANDE, Daniel
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorSIX, J.L.
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorBREUNIG, Stephan
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorHÉROGUEZ, Valérie
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorFONTANILLE, Michel
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorGNANOU, Yves
dc.date.accessioned2020
dc.date.available2020
dc.date.issued1998
dc.identifier.issn1042-7147
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19567
dc.description.abstractEnThis paper reviews the possibilities of engineering novel macromolecular topologies via ªlivingº ring-opening metathesis polymerization (ROMP) of miscellaneous macromonomers. It is shown that multibranched polystyrene poly(ethylene oxide) and polybutadiene poly-macromonomers of varying compactness and branch number can be prepared by ROMP of corresponding macromonomers, provided the macromonomers carry an end-standing norbornene unsaturation. Janus-type ar-chitectures are also accessible by this technique: such entirely novel topologies can be obtained by sequential ROMP of two different macromonomers whereas their statistical copolymerization affords heteroarmed macro-molecules. Advantage has also been taken of the versatility of this technique to prepare compact polymeric architectures that behave like unimicellar systems: structures whose inner part and outer layer are chemically different can be derived through homopoly-merization of macromonomers that are themselves block copolymers.
dc.language.isoen
dc.publisherWiley
dc.subject.ennorbornene-ended macromonomers
dc.subject.enring- opening metathesis polymerization
dc.subject.enpolymacro- monomers
dc.subject.enJanus-type architecture
dc.subject.enheteroarmed sphere
dc.title.enPolymers with novel topologies by ring-opening metathesis polymerization of macromonomers
dc.typeArticle de revue
dc.identifier.doi10.1002/(SICI)1099-1581(1998100)9:10/11<601::AID-PAT835>3.0.CO;2-P
dc.subject.halChimie/Polymères
bordeaux.journalPolymers for Advanced Technologies
bordeaux.page601-612
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue9
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-02945706
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02945706v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Polymers%20for%20Advanced%20Technologies&amp;rft.date=1998&amp;rft.issue=9&amp;rft.spage=601-612&amp;rft.epage=601-612&amp;rft.eissn=1042-7147&amp;rft.issn=1042-7147&amp;rft.au=GRANDE,%20Daniel&amp;SIX,%20J.L.&amp;BREUNIG,%20Stephan&amp;HE%CC%81ROGUEZ,%20Vale%CC%81rie&amp;FONTANILLE,%20Michel&amp;rft.genre=article


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