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Incorporation of magnetic nanoparticles into lamellar polystyrene-b-poly(n-butyl methacrylate) diblock copolymer films: influence of the chain end-groups on nanostructuration

dc.rights.licenseopen
hal.structure.identifierPhysicochimie des Electrolytes, Colloïdes et Sciences Analytiques [PECSA]
dc.contributor.authorDOUADI-MASROUKI, Siham
hal.structure.identifierPhysicochimie des Electrolytes, Colloïdes et Sciences Analytiques [PECSA]
dc.contributor.authorFRKA-PETESIC, Bruno
hal.structure.identifierInstitut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM]
hal.structure.identifierChimie des polymères [LCP]
dc.contributor.authorSAVE, Maud
hal.structure.identifierChimie des polymères [LCP]
hal.structure.identifierLaboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265 [C2P2]
dc.contributor.authorCHARLEUX, Bernadette
hal.structure.identifierPhysicochimie des Electrolytes, Colloïdes et Sciences Analytiques [PECSA]
hal.structure.identifierPHysicochimie des Electrolytes et Nanosystèmes InterfaciauX [PHENIX]
dc.contributor.authorCABUIL, Valérie
hal.structure.identifierTeam 3 LCPO : Polymer Self-Assembly & Life Sciences
hal.structure.identifierLaboratoire de Chimie des Polymères Organiques [LCPO]
dc.contributor.authorSANDRE, Olivier
dc.date.accessioned2020
dc.date.available2020
dc.date.issued2010
dc.identifier.issn0032-3861
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/19555
dc.description.abstractEnIn this article, we present new samples of lamellar magnetic nanocomposites based on the self-assembly of a polystyrene-b-poly(n-butyl methacrylate) diblock copolymer synthesized by atom transfer radical polymerization. The polymer films were loaded with magnetic iron oxide nanoparticles covered with polystyrene chains grown by surface initiated-ATRP. The nanostructuration of the pure and magnetically loaded copolymer films on silicon was studied by atomic force microscopy, ellipsometry, neutron reflectivity and contact angle measurement. The present study highlights the strong influence of the copolymer extremity - driven itself by the choice of the ATRP chemical route - on the order of the repetition sequences of the blocks in the multi-lamellar films. In addition, a narrower distribution of the nanoparticles' sizes was examined as a control parameter of the SI-ATRP reaction.
dc.language.isoen
dc.publisherElsevier
dc.subject.enMaghemite Core-Polystyrene Shell
dc.subject.enBlock copolymers
dc.subject.enPolymer Physical Chemistry
dc.subject.enPolymer Synthesis
dc.subject.enPolymer Composite Materials
dc.subject.enLamellar structure
dc.subject.enNeutron reflectivity
dc.subject.enPolystyrene-b-poly(n-butyl methacrylate)
dc.subject.enMagnetic Nanoparticles
dc.subject.enGrafting-from Polymerization
dc.subject.enAtom Transfer Radical Polymerization
dc.title.enIncorporation of magnetic nanoparticles into lamellar polystyrene-b-poly(n-butyl methacrylate) diblock copolymer films: influence of the chain end-groups on nanostructuration
dc.typeArticle de revue
dc.identifier.doi10.1016/j.polymer.2010.08.043
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci]
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Matière Molle [cond-mat.soft]
dc.subject.halChimie/Matériaux
dc.subject.halChimie/Polymères
dc.identifier.arxiv1809.07063
bordeaux.journalPolymer
bordeaux.page4673-4685
bordeaux.volume51
bordeaux.hal.laboratoriesLaboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629*
bordeaux.issue21
bordeaux.institutionBordeaux INP
bordeaux.institutionUniversité de Bordeaux
bordeaux.peerReviewedoui
hal.identifierhal-00516975
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00516975v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polymer&rft.date=2010&rft.volume=51&rft.issue=21&rft.spage=4673-4685&rft.epage=4673-4685&rft.eissn=0032-3861&rft.issn=0032-3861&rft.au=DOUADI-MASROUKI,%20Siham&FRKA-PETESIC,%20Bruno&SAVE,%20Maud&CHARLEUX,%20Bernadette&CABUIL,%20Val%C3%A9rie&rft.genre=article


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