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Impurity tolerance of polymer solar cells: The crucial role of palladium catalyst and its ligands

hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorROCHE, Gilles
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorVIOLLET, Lucas
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPENIN, Nicolas
hal.structure.identifierSeqens SAS [Seqens]
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorJOUSSELIN-OBA, Tanguy
hal.structure.identifierSeqens SAS [Seqens]
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorDINDAULT, Chloé
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorVIGNAU, Laurence
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorCHAMBON, Sylvain
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorHIRSCH, Lionel
hal.structure.identifierSeqens SAS [Seqens]
dc.contributor.authorBONNARDEL, Pierre-Antoine
hal.structure.identifierSeqens SAS [Seqens]
dc.contributor.authorTAILLEMITE, Sébastien
hal.structure.identifierLaboratoire de l'intégration, du matériau au système [IMS]
dc.contributor.authorWANTZ, Guillaume
dc.date.accessioned2024-03-05T03:10:12Z
dc.date.available2024-03-05T03:10:12Z
dc.date.issued2024
dc.identifier.issn0927-0248
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/188572
dc.description.abstractEnPolymer photovoltaic solar cells based on PTQ10:IT4F were fabricated and characterized with voluntary contamination of several impurities in various amounts. Impurities were selected as related to the Stille coupling reagents: in particular palladium catalysts and their respective ligands. Below a concentration of 300 ppm, the pristine device efficiencies were not significantly affected for any of the studied compounds. The degradation patterns under accelerated light soaking were not modified either. For higher impurities amounts (>300 ppm), Pd(PPh3)4 catalyst shows a strong poisoning effect on both pristine device performances and operating stability. Interestingly, we demonstrate that not only the metallic center of the catalytic complex, but also the ligands can play a role on the organic solar cells performances.
dc.description.sponsorshipLaboratoire des Semi-conducteurs Photoactifs Robustes Imprimables pour les Nouvelles Technologies - ANR-19-LCV1-0006
dc.language.isoen
dc.publisherElsevier
dc.subject.enCatalyst traces
dc.subject.enImpurities
dc.subject.enOrganic solar cells
dc.subject.enLigand
dc.subject.enStability
dc.title.enImpurity tolerance of polymer solar cells: The crucial role of palladium catalyst and its ligands
dc.typeArticle de revue
dc.identifier.doi10.1016/j.solmat.2024.112760
dc.subject.halChimie/Matériaux
bordeaux.journalSolar Energy Materials and Solar Cells
bordeaux.page112760
bordeaux.volume269
bordeaux.hal.laboratoriesInstitut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026*
bordeaux.institutionUniversité de Bordeaux
bordeaux.institutionBordeaux INP
bordeaux.institutionCNRS
bordeaux.peerReviewedoui
hal.identifierhal-04488675
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-04488675v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Solar%20Energy%20Materials%20and%20Solar%20Cells&rft.date=2024&rft.volume=269&rft.spage=112760&rft.epage=112760&rft.eissn=0927-0248&rft.issn=0927-0248&rft.au=ROCHE,%20Gilles&VIOLLET,%20Lucas&PENIN,%20Nicolas&JOUSSELIN-OBA,%20Tanguy&DINDAULT,%20Chlo%C3%A9&rft.genre=article


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