A Raman Spectroscopic Study of Nitromethane up to 350 °C and 35 GPa
| hal.structure.identifier | Centre d'Etudes de Vaujours-Moronvilliers | |
| dc.contributor.author | COURTECUISSE, S. | |
| hal.structure.identifier | Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP] | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| hal.structure.identifier | Laboratoire de Chimie du Solide | |
| dc.contributor.author | CANSELL, François | |
| hal.structure.identifier | Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP] | |
| dc.contributor.author | FABRE, D. | |
| hal.structure.identifier | Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions [LIMHP] | |
| dc.contributor.author | PETITET, J.-P. | |
| dc.date.created | 1995 | |
| dc.date.issued | 1995 | |
| dc.identifier.issn | 1155-4339 | |
| dc.description.abstractEn | Nitromethane has been studied as a model of the energetic nitro materials. The liquid - transition line has been established by Piermarini [1] and a first solid - solid transition corresponding to the methyl group rotation locking has been evidenced by Cromer [2]. In order to precise the phase diagram of nitromethane, a study has been performed by Raman scattering in the pressure and temperature range of 0 -35 GPa and 20 - 350°C respectively. From these experimental results three new solid phases of nitromethane called III, IV, V and their stability domain have been located. A first chemical transformation line has been detected by the disappearance of nitromethane Raman modes and by the irreversible formation of a transparent solid (CI). A second chemical transformation (CI - CII), at higher temperature, is observed by the sudden darkening of the sample. | |
| dc.language.iso | en | |
| dc.publisher | EDP Sciences | |
| dc.subject.en | Nitromethane | |
| dc.subject.en | Raman spectroscopy | |
| dc.subject.en | High pressure | |
| dc.title.en | A Raman Spectroscopic Study of Nitromethane up to 350 °C and 35 GPa | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1051/jp4:1995428 | |
| dc.subject.hal | Physique [physics]/Articles anciens | |
| bordeaux.journal | Journal de Physique IV Proceedings | |
| bordeaux.page | 359-363 | |
| bordeaux.volume | 5 | |
| bordeaux.issue | C4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | jpa-00253733 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//jpa-00253733v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20de%20Physique%20IV%20Proceedings&rft.date=1995&rft.volume=5&rft.issue=C4&rft.spage=359-363&rft.epage=359-363&rft.eissn=1155-4339&rft.issn=1155-4339&rft.au=COURTECUISSE,%20S.&CANSELL,%20Fran%C3%A7ois&FABRE,%20D.&PETITET,%20J.-P.&rft.genre=article |
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