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Nanoscale multilayered and porous carbide interphases prepared by pressure-pulsed reactive chemical vapor deposition for ceramic matrix composites

dc.rights.licenseopenen_US
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorJACQUES, Sylvain
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorJOUANNY, I.
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorLEDAIN, Olivier
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorMAILLE, Laurence
hal.structure.identifierLaboratoire des Composites Thermostructuraux [LCTS]
dc.contributor.authorWEISBECKER, Patrick
dc.date.accessioned2023-10-24T08:54:54Z
dc.date.available2023-10-24T08:54:54Z
dc.date.issued2013-06-15
dc.identifier.issn0169-4332en_US
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/184509
dc.description.abstractEnIn Ceramic Matrix Composites (CMCs) reinforced by continuous fibers, a good toughness is achieved by adding a thin film called “interphase” between the fiber and the brittle matrix, which acts as a mechanical fuse by deflecting the matrix cracks. Pyrocarbon (PyC), with or without carbide sub-layers, is typically the material of choice to fulfill this role. The aim of this work was to study PyC-free nanoscale multilayered carbide coatings as interphases for CMCs. Nanoscale multilayered (SiC–TiC)n interphases were deposited by pressure-Pulsed Chemical Vapor Deposition (P-CVD) on single filament Hi-Nicalon fibers and embedded in a SiC matrix sheath. The thicknesses of the carbide interphase sub-layers could be made as low as a few nanometers as evidenced by scanning and transmission electron microscopy. By using the P-ReactiveCVD method (P-RCVD), in which the TiC growth involves consumption of SiC, it was not only possible to obtain multilayered (SiC–TiC)n films but also TiC films with a porous multilayered microstructure as a result of the Kirkendall effect. The porosity in the TiC sequences was found to be enhanced when some PyC was added to SiC prior to total RCVD consumption. Because the porosity volume fraction was still not high enough, the role of mechanical fuse of the interphases could not be evidenced from the tensile curves, which remained fully linear even when chemical attack of the fiber surface was avoided.
dc.language.isoENen_US
dc.subject.enInterphase
dc.subject.enCMC
dc.subject.enReactive CVD
dc.subject.enMultilayer
dc.subject.enCarbide
dc.subject.enPorosity
dc.title.enNanoscale multilayered and porous carbide interphases prepared by pressure-pulsed reactive chemical vapor deposition for ceramic matrix composites
dc.title.alternativeAppl Surf Scien_US
dc.typeArticle de revueen_US
dc.identifier.doi10.1016/j.apsusc.2013.01.100en_US
dc.subject.halChimieen_US
dc.subject.halChimie/Matériauxen_US
bordeaux.journalApplied Surface Scienceen_US
bordeaux.page102 - 109en_US
bordeaux.volume275en_US
bordeaux.hal.laboratoriesLaboratoire des Composites Thermo Structuraux (LCTS) - UMR 5801en_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.institutionCNRSen_US
bordeaux.institutionCEAen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.import.sourcehal
hal.identifierhal-01845088
hal.version1
hal.popularnonen_US
hal.audienceInternationaleen_US
hal.exportfalse
workflow.import.sourcehal
dc.rights.ccPas de Licence CCen_US
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Applied%20Surface%20Science&rft.date=2013-06-15&rft.volume=275&rft.spage=102%20-%20109&rft.epage=102%20-%20109&rft.eissn=0169-4332&rft.issn=0169-4332&rft.au=JACQUES,%20Sylvain&JOUANNY,%20I.&LEDAIN,%20Olivier&MAILLE,%20Laurence&WEISBECKER,%20Patrick&rft.genre=article


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