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Towards the additive manufacturing of Zr-based metallic glasses using liquid phase sintering: Reactivity and phase transformation kinetics at the crystalline/amorphous interface

hal.structure.identifierMatériaux, ingénierie et science [Villeurbanne] [MATEIS]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPONTOREAU, Maël
hal.structure.identifierLaboratoire des Multimatériaux et Interfaces [LMI]
dc.contributor.authorDEZELLUS, Olivier
hal.structure.identifierMatériaux, ingénierie et science [Villeurbanne] [MATEIS]
dc.contributor.authorCARDINAL, Sandrine
hal.structure.identifierMatériaux, ingénierie et science [Villeurbanne] [MATEIS]
dc.contributor.authorPELLETIER, Jean-Marc
hal.structure.identifierLaboratoire des Multimatériaux et Interfaces [LMI]
dc.contributor.authorCHIRIAC, Rodica
hal.structure.identifierLaboratoire des Multimatériaux et Interfaces [LMI]
dc.contributor.authorTOCHE, Francois
hal.structure.identifierMatériaux, ingénierie et science [Villeurbanne] [MATEIS]
dc.contributor.authorSTEYER, Philippe
hal.structure.identifierMatériaux, ingénierie et science [Villeurbanne] [MATEIS]
dc.contributor.authorGREMILLARD, Laurent
hal.structure.identifierMatériaux, ingénierie et science [Villeurbanne] [MATEIS]
dc.contributor.authorVALLÉE, Maxime
hal.structure.identifierMatériaux, ingénierie et science [Villeurbanne] [MATEIS]
dc.contributor.authorBOULNAT, X
dc.date.issued2023
dc.identifier.issn0925-8388
dc.description.abstractEnBulk metallic glasses (BMG) present great potential for high-tech applications considering the excellent mechanical and corrosion properties. The on-going development of powder additive manufacturing techniques offers the opportunity to produce rather large parts composed of BMG. Relative to the sinter based additive manufacturing techniques, the sintering of a Zr-based BMG (AMZ4, Zr59,3Cu28,8Al10,4Nb1,5) using Zn-based additives was identified as promising: Zn alloys have indeed a melting point (Tm,Zn = 419, 5∘C) lower than the crystallization temperature of the BMG (Tx ≃ 470∘C). Here, the study focuses on the understanding of the reactivity between AMZ4 and Zn as a function of temperature and time. A powder blend and a model interface AMZ4/Zn were studied combining post-mortem characterizations (SEM, EDX, XRD, micro-hardness…) with in situ characterization (DSC). Experimental construction of time-temperature-transformation diagram shows that there is a temperature/time window where sintering is permitted without crystallization. Beyond, an intermetallic phase is formed at the interface between the BMG and Zn, this phase was identified in terms of shape, composition and crystallography. A growth mechanism was proposed combining thermodynamic and kinetic aspects.
dc.description.sponsorshipSurface & Interface Science & Engineering - ANR-10-LABX-0075
dc.description.sponsorshipPROJET AVENIR LYON SAINT-ETIENNE - ANR-11-IDEX-0007
dc.language.isoen
dc.publisherElsevier
dc.subject.enMetallic glasses
dc.subject.enPowder metallurgy
dc.subject.enSintering
dc.subject.enDiffusion
dc.subject.enThermal analysis
dc.subject.enScanning electron microscopy
dc.title.enTowards the additive manufacturing of Zr-based metallic glasses using liquid phase sintering: Reactivity and phase transformation kinetics at the crystalline/amorphous interface
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jallcom.2023.171179
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Alloys and Compounds
bordeaux.page171179
bordeaux.volume962
bordeaux.peerReviewedoui
hal.identifierhal-04151331
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-04151331v1
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