Systematic XPS studies of metal oxides, hydroxides and peroxides
| hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
| dc.contributor.author | DUPIN, Jean-Charles | |
| hal.structure.identifier | Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux [IPREM] | |
| dc.contributor.author | GONBEAU, Danielle | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | VINATIER, Philippe | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LEVASSEUR, Alain | |
| dc.date.issued | 2000 | |
| dc.identifier.issn | 1463-9076 | |
| dc.description.abstractEn | The results of a systematic XPS study, under high controlled conditions, of different basic oxides of transition metals, alkali and alkaline-earth metals are presented; the XPS data of some hydroxides and peroxides are also reported. Variations of the O 1s binding energies are analysed and one point of interest is the large binding energy scale obtained for O 1s peaks all associated with a '2-' formal charge. Through extended Huckel theory-tight binding (EHT-TB) calculations, attempts are made to rationalize the observed variations. The results illustrate the significant differences between real charges on oxygen atoms in transition metal and alkaline-earth oxides. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.title.en | Systematic XPS studies of metal oxides, hydroxides and peroxides | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/a908800h | |
| dc.subject.hal | Chimie/Matériaux | |
| dc.subject.hal | Chimie/Chimie inorganique | |
| bordeaux.journal | Physical Chemistry Chemical Physics | |
| bordeaux.page | 1319-1324 | |
| bordeaux.volume | 2 | |
| bordeaux.issue | 6 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01636425 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01636425v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Physical%20Chemistry%20Chemical%20Physics&rft.date=2000&rft.volume=2&rft.issue=6&rft.spage=1319-1324&rft.epage=1319-1324&rft.eissn=1463-9076&rft.issn=1463-9076&rft.au=DUPIN,%20Jean-Charles&GONBEAU,%20Danielle&VINATIER,%20Philippe&LEVASSEUR,%20Alain&rft.genre=article |
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