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Room temperature control of spin states in a thin film of a photochromic iron(II) complex

hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPOGGINI, Lorenzo
hal.structure.identifierDepartment of Chemistry and Pharmacy
dc.contributor.authorMILEK, Magdalena
hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
dc.contributor.authorLONDI, Giacomo
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorNAÏM, Ahmad
hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
dc.contributor.authorPONETI, Giordano
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSQUILLANTINI, Lorenzo
hal.structure.identifierDepartment of Biotechnologies, Chemistry and Pharmacy
dc.contributor.authorMAGNANI, Agnese
hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
dc.contributor.authorTOTTI, Federico
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROSA, Patrick
hal.structure.identifierDepartment of Chemistry and Pharmacy
dc.contributor.authorKHUSNIYAROV, Marat
hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
dc.contributor.authorMANNINI, Matteo
dc.date.issued2018
dc.identifier.issn2051-6347
dc.description.abstractEnThin films of a molecular spin crossover iron(II) complex featuring a photochromic diarylethene-based ligand have been grown by sublimation in ultra-high vacuum on an Au(111) single crystal, and investigated by X-ray and UV photoelectron spectroscopies. Temperature-dependent studies demonstrate that the thermally induced spin crossover behaviour is preserved in thin films. The photochromic ligand deliberately integrated into the complex allows photoswitching of the spin states of this iron(II) complex at room temperature, and this photomagnetic effect is still observed in 5 nm thick sublimated films. Thus, this work opens new horizons and pushes bistable spin crossover systems closer to prospective applications in molecular electronics and molecular spintronics devices functioning at room temperature.
dc.description.sponsorshipSynthèse, caractérisation et mesures Optiques sur composés CHIRaux à Transition de Spin
dc.language.isoen
dc.publisherthe Royal Society of Chemistry
dc.title.enRoom temperature control of spin states in a thin film of a photochromic iron(II) complex
dc.typeArticle de revue
dc.identifier.doi10.1039/C7MH01042G
dc.subject.halChimie/Matériaux
bordeaux.journalMaterials Horizons
bordeaux.page506-513
bordeaux.volume5
bordeaux.issue3
bordeaux.peerReviewedoui
hal.identifierhal-01797021
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01797021v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Materials%20Horizons&rft.date=2018&rft.volume=5&rft.issue=3&rft.spage=506-513&rft.epage=506-513&rft.eissn=2051-6347&rft.issn=2051-6347&rft.au=POGGINI,%20Lorenzo&MILEK,%20Magdalena&LONDI,%20Giacomo&NA%C3%8FM,%20Ahmad&PONETI,%20Giordano&rft.genre=article


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