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hal.structure.identifierLaboratoire de Physico-Chimie Théorique [LPCT]
dc.contributor.authorDÉMERY, V.
hal.structure.identifierLaboratoire de Physico-Chimie Théorique [LPCT]
dc.contributor.authorMONSARRAT, R.
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorDEAN, David S.
hal.structure.identifierDepartment of Physics, Faculty of Mathematics and Physics
hal.structure.identifierDepartment of Theoretical Physics
dc.contributor.authorPODGORNIK, R.
dc.date.created2015-11-23
dc.date.issued2016-01
dc.identifier.issn0295-5075
dc.description.abstractEnThe exact solution, via transfer matrix, of the simple one dimensional lattice Coulomb gas (1d LCG) model can reproduce peculiar features of ionic liquid capacitors, such as overscreening, layering, and camel- and bell-shaped capacitance curves. Using the same transfer matrix method, we now compute the bulk properties of the 1d LCG in the constant voltage ensemble. We unveil a phase diagram with rich structure exhibiting a low density disordered and high density ordered phases, separated by a first order phase transition at low temperature; the solid state at full packing can be ordered or not, depending on the temperature. This phase diagram, which is strikingly similar to its three dimensional counterpart, also sheds light on the behaviour of the confined system.
dc.language.isoen
dc.publisherEuropean Physical Society/EDP Sciences/Società Italiana di Fisica/IOP Publishing
dc.rights.urihttp://creativecommons.org/licenses/by-sa/
dc.subject.enElectrolytes
dc.subject.enStatistical mechanics of classical fluids
dc.subject.enPhas transitions: general studies
dc.title.enPhase diagram of a bulk 1d lattice Coulomb gas
dc.typeArticle de revue
dc.identifier.doi10.1209/0295-5075/113/18008
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Mécanique statistique [cond-mat.stat-mech]
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Matière Molle [cond-mat.soft]
dc.identifier.arxiv1511.07170
bordeaux.journalEPL - Europhysics Letters
bordeaux.page18008 (1-6)
bordeaux.volume113
bordeaux.issue1
bordeaux.peerReviewedoui
hal.identifierhal-01284082
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01284082v1
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