Nonlinear optical properties and application of a chiral and photostimulable iron(II) compound
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | IAZZOLINO, A | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | OULD HAMOUDA, A | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | NAÏM, Ahmad | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | STEFÁNCZYK, Olaf | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | ROSA, Patrick | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | FREYSZ, Eric | |
| dc.date.created | 2017-02 | |
| dc.date.issued | 2017 | |
| dc.identifier.issn | 0003-6951 | |
| dc.description.abstractEn | We measure linear absorption, circular dichroïsm, second harmonic and sum frequency generation in the [-Fe(phen) 3 ](Δ-As 2 (tartarate) 2), [-Fe(phen) 3 ](-As 2 (tartarate) 2) enantiomers of an Fe(II) complex. In the solid state, the chirality of this compound results from the introduction of the (As 2 (tartarate) 2) chiral anions. Linear absorption and X-ray diffraction indicate that Fe(II) is in the low-spin state. Circular dichroïsm reveals that in the solid state, these compounds are chiral, whereas the complexes racemize in solution. A large second harmonic generation signal is recorded using thin films from these two enantiomers. The second-order susceptibility of these compounds is evaluated across the visible spectral range. It displays a resonance at 520 nm, which is associated with the metal-to-ligand charge transfer occurring within the complex. At its maximum, = 6.4 pm V-1 is more than 1.4 times larger than the well-known beta-BaB 2 O 4 nonlinear crystal (~4.4 pm V-1). Finally, we demonstrate a useful application for a thin film from this compound, which characterizes the cross-correlation of two femtosecond laser pulses. | |
| dc.language.iso | en | |
| dc.publisher | American Institute of Physics | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/ | |
| dc.title.en | Nonlinear optical properties and application of a chiral and photostimulable iron(II) compound | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1063/1.4981254 | |
| dc.subject.hal | Physique [physics]/Physique [physics]/Optique [physics.optics] | |
| dc.subject.hal | Sciences de l'ingénieur [physics]/Matériaux | |
| dc.subject.hal | Sciences de l'ingénieur [physics]/Optique / photonique | |
| bordeaux.journal | Applied Physics Letters | |
| bordeaux.page | 161908 (5 p.) | |
| bordeaux.volume | 110 | |
| bordeaux.issue | 16 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01507147 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01507147v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Applied%20Physics%20Letters&rft.date=2017&rft.volume=110&rft.issue=16&rft.spage=161908%20(5%20p.)&rft.epage=161908%20(5%20p.)&rft.eissn=0003-6951&rft.issn=0003-6951&rft.au=IAZZOLINO,%20A&OULD%20HAMOUDA,%20A&NA%C3%8FM,%20Ahmad&STEF%C3%81NCZYK,%20Olaf&ROSA,%20Patrick&rft.genre=article |
Fichier(s) constituant ce document
| Fichiers | Taille | Format | Vue |
|---|---|---|---|
|
Il n'y a pas de fichiers associés à ce document. |
|||