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Long-range interactions of surface charges on electrolyte films
| hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
| dc.contributor.author | FORET, Lionel | |
| hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
| dc.contributor.author | WÜRGER, Aloïs | |
| dc.contributor.editor | Cabuil | |
| dc.contributor.editor | V. and Levitz | |
| dc.contributor.editor | P. and Treiner | |
| dc.contributor.editor | C. | |
| dc.date.issued | 2004 | |
| dc.date.conference | 2002-09 | |
| dc.description.abstractEn | A surface charge at an electrolyte–insulator interface and its counterion cloud form an electric dipole, thus giving rise to a long-range interaction that has been identified as the usual dipolar interaction. In this paper, we show that the picture of interacting dipoles ceases to be valid for a thin film with a thickness smaller than the Debye screening length. Indeed, in this case, both parallel and antiparallel dipoles repel each other, with a force much stronger than expected from a dipolar interaction. This originates from the delocalization of the screening clouds in very thin films. | |
| dc.language.iso | en | |
| dc.publisher | Springer-Verlag Berlin | |
| dc.subject.en | Counterion Distribution | |
| dc.subject.en | Debye Screening Length | |
| dc.subject.en | Discrete Charge | |
| dc.subject.en | Dipole Picture | |
| dc.subject.en | Opposite Interface | |
| dc.title.en | Long-range interactions of surface charges on electrolyte films | |
| dc.type | Communication dans un congrès | |
| dc.identifier.doi | 10.1007/b93985 | |
| dc.subject.hal | Physique [physics]/Matière Condensée [cond-mat]/Matière Molle [cond-mat.soft] | |
| bordeaux.page | 114-116 | |
| bordeaux.volume | 126 | |
| bordeaux.country | FR | |
| bordeaux.conference.city | Paris | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01550802 | |
| hal.version | 1 | |
| hal.invited | non | |
| hal.proceedings | oui | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01550802v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.date=2004&rft.volume=126&rft.spage=114-116&rft.epage=114-116&rft.au=FORET,%20Lionel&W%C3%9CRGER,%20Alo%C3%AFs&rft.genre=unknown |
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