A photochemical electrocyclization of the benzothiazolylphenylethenes involving a C-N bond formation
| hal.structure.identifier | Photochemistry Center [Moscou] | |
| dc.contributor.author | FEDOROVA, O. A. | |
| hal.structure.identifier | Photochemistry Center [Moscou] | |
| dc.contributor.author | GULAKOVA, E. N. | |
| hal.structure.identifier | Photochemistry Center [Moscou] | |
| dc.contributor.author | FEDOROY, Y. V. | |
| hal.structure.identifier | Photochemistry Center [Moscou] | |
| dc.contributor.author | LOBAZOVA, I. E. | |
| hal.structure.identifier | Photochemistry Center [Moscou] | |
| dc.contributor.author | ALFIRNOV, M. V. | |
| hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
| dc.contributor.author | JONUSAUSKAS, Gediminas | |
| dc.date.issued | 2008-05-20 | |
| dc.identifier.issn | 1010-6030 | |
| dc.description.abstractEn | A novel oxidative photodehydrocyclization of benzothiazolylphenylethenes to a polycyclic heteroaromatic cations with good yields was described. Starting from the trans-derivative, the phototransformation is a multistep process. It includes two photochemical reactions, a trans-cis-isomerization reaction followed by an 1-aza-1,3,5-hexatrienic electrocyclic reaction involving the formation of CN bond. The cyclized product gives the stable heteroaromatic cations from hydride elimination with oxygen from air. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Electrocyclic reaction | |
| dc.subject.en | Photocyclization | |
| dc.subject.en | 2-Styrybenzothiazoles | |
| dc.subject.en | Crown ethers | |
| dc.subject.en | Benzothiazolo[3 | |
| dc.subject.en | 2-a]quinolines | |
| dc.title.en | A photochemical electrocyclization of the benzothiazolylphenylethenes involving a C-N bond formation | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.jphotochem.2007.07.036 | |
| dc.subject.hal | Physique [physics] | |
| dc.subject.hal | Physique [physics]/Physique [physics]/Optique [physics.optics] | |
| bordeaux.journal | Journal of Photochemistry and Photobiology A: Chemistry | |
| bordeaux.page | 239-245 | |
| bordeaux.volume | 196 | |
| bordeaux.issue | 2-3 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01552916 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01552916v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Photochemistry%20and%20Photobiology%20A:%20Chemistry&rft.date=2008-05-20&rft.volume=196&rft.issue=2-3&rft.spage=239-245&rft.epage=239-245&rft.eissn=1010-6030&rft.issn=1010-6030&rft.au=FEDOROVA,%20O.%20A.&GULAKOVA,%20E.%20N.&FEDOROY,%20Y.%20V.&LOBAZOVA,%20I.%20E.&ALFIRNOV,%20M.%20V.&rft.genre=article |
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