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Transient absorption spectroscopy of the [Fe(2 CH3-phen)3]2+ complex: Study of the high spin ↔ low spin relaxation of an isolated iron(II) complex

hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorGALLÉ, Geoffrey
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorJONUSAUSKAS, Gediminas
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorTONDUSSON, Marc
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMAURIAC, Cindy
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLETARD, Jean-François
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorFREYSZ, Eric
dc.date.created2012-09-14
dc.date.issued2013
dc.identifier.issn0009-2614
dc.description.abstractEnWe report on the light induced spin crossover dynamics of [Fe(2 CH3-phen)3]2+ complex in solution. The excitation of the complex by pulses centered at λ = 500 nm along the metal to ligand charge transfer absorption band indicates a selective excitation of the LS state. The excitation of the complex by pulses centered at λ = 330 nm or λ = 335 nm reveals an increase of the LS state population and a photo-bleaching of the HS state population that is associated to a transient photo-dissociation. A method that makes it possible to deduce the kinetics of both the HS → LS state and LS → HS state is proposed.
dc.description.sponsorship/
dc.language.isoen
dc.publisherElsevier
dc.rights.urihttp://creativecommons.org/licenses/by-nc/
dc.title.enTransient absorption spectroscopy of the [Fe(2 CH3-phen)3]2+ complex: Study of the high spin ↔ low spin relaxation of an isolated iron(II) complex
dc.typeArticle de revue
dc.identifier.doi10.1016/J.CPLETT.2012.11.034
dc.subject.halChimie/Chimie théorique et/ou physique
dc.subject.halChimie/Chimie de coordination
bordeaux.journalChemical Physics Letters
bordeaux.page82-88
bordeaux.volume556
bordeaux.peerReviewedoui
hal.identifierhal-00788820
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00788820v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Physics%20Letters&rft.date=2013&rft.volume=556&rft.spage=82-88&rft.epage=82-88&rft.eissn=0009-2614&rft.issn=0009-2614&rft.au=GALL%C3%89,%20Geoffrey&JONUSAUSKAS,%20Gediminas&TONDUSSON,%20Marc&MAURIAC,%20Cindy&LETARD,%20Jean-Fran%C3%A7ois&rft.genre=article


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