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High-pressure properties inferred from normal-pressure properties

hal.structure.identifierDepartament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB]
dc.contributor.authorTAMARIT, Jose Luis
hal.structure.identifierDepartament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB]
dc.contributor.authorBARRIO, María
hal.structure.identifierDepartament de Fisica i Enginyeria Nuclear [UPC, Barcelone] [ETSEIB]
hal.structure.identifierInstitut für Kernphysik [IKP]
dc.contributor.authorPARDO, Luis C.
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorNÉGRIER, Philippe
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorMONDIEIG, Denise
dc.date.created2008-02-29
dc.date.issued2008-05-29
dc.identifier.issn0953-8984
dc.description.abstractEnFrom the stable and metastable normal-pressure phase equilibria involved in two-component systems sharing compounds of the series CCl4-nBrn, n = 0,..., 4, several thermodynamic properties concerning non-experimentally available phase transitions have been determined. To do so, the well-established concept of crossed isodimorphism has been considered to involve the isomorphism relationships between the low-temperature monoclinic phases as well as, for both rhombohedral and face-centred cubic, orientationally disordered phases appearing in the compounds of the series. On the basis of such relations, the thermodynamic properties of the two-phase equilibria are extrapolated as a function of mole fraction to the pure compounds for which the involved transitions do not exist at normal pressure. The obtained thermodynamic properties are used to build up the topological pressure-temperature phase diagrams of the compounds of the series. The results are compared with the experimental pressure-temperature phase diagrams obtained by means of density measurements as a function of pressure and temperature.
dc.language.isoen
dc.publisherIOP Publishing
dc.title.enHigh-pressure properties inferred from normal-pressure properties
dc.typeArticle de revue
dc.identifier.doi10.1088/0953-8984/20/24/244110
bordeaux.journalJournal of Physics: Condensed Matter
bordeaux.page244110 (1-8)
bordeaux.volume20
bordeaux.issue24
bordeaux.peerReviewedoui
hal.identifierhal-00745980
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00745980v1
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