Specific features of reversible E--Z-photoisomerization of crown-containing 4-styrylpyridine complexes with various cations
| hal.structure.identifier | A. N. Nesmeyanov Institute of Organoelement Compounds [INEOS] | |
| dc.contributor.author | FEDOROV, Yuri V. | |
| hal.structure.identifier | A. N. Nesmeyanov Institute of Organoelement Compounds [INEOS] | |
| dc.contributor.author | SHEPEL, N. E. | |
| hal.structure.identifier | A. N. Nesmeyanov Institute of Organoelement Compounds [INEOS] | |
| dc.contributor.author | CHERNIKOVA, Ekaterina Yu. | |
| hal.structure.identifier | A. N. Nesmeyanov Institute of Organoelement Compounds [INEOS] | |
| dc.contributor.author | FEDOROVA, Olga A. | |
| hal.structure.identifier | A. N. Nesmeyanov Institute of Organoelement Compounds [INEOS] | |
| dc.contributor.author | GULAKOVA, Elena N. | |
| hal.structure.identifier | Photochemistry Center | |
| dc.contributor.author | AVAKYAN, V. G. | |
| hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
| dc.contributor.author | JONUSAUSKAS, Gediminas | |
| dc.date.created | 2008-04-30 | |
| dc.date.issued | 2008-11-18 | |
| dc.identifier.issn | 1066-5285 | |
| dc.description.abstractEn | The reversible photochemical E--Z-isomerization of crown-containing 4-styrylpyridine was studied. The reaction was carried out in the presence of alkaline-earth metals capable of forming complexes with the crown-ether fragment and heavy metal perchlorates (Hg2+, Cd2+) that are able to coordinate the nitrogen atom of the heterocyclic residue. The influence of complex formation on the E--Z-photoisomerization was determined by electronic spectroscopy and 1H NMR spectroscopy. The studies performed confirm that the E--Z-photoisomerization can be controlled using supramolecular complex formation. | |
| dc.language.iso | en | |
| dc.publisher | Springer Verlag | |
| dc.subject.en | mercury perchlorate | |
| dc.subject.en | 15-crown-5 ethe | |
| dc.subject.en | crown-containing styrylpyridine | |
| dc.subject.en | E--Z-photoisomerization | |
| dc.subject.en | complex formation | |
| dc.subject.en | alkaline-earth metal perchlorates | |
| dc.subject.en | cadmium perchlorate | |
| dc.subject.en | mercury perchlorate. | |
| dc.title.en | Specific features of reversible E--Z-photoisomerization of crown-containing 4-styrylpyridine complexes with various cations | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1007/s11172-008-0340-0 | |
| dc.subject.hal | Physique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph] | |
| bordeaux.journal | Russian Chemical Bulletin | |
| bordeaux.page | 2385-2393 | |
| bordeaux.volume | 57 | |
| bordeaux.issue | 11 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00747017 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00747017v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Russian%20Chemical%20Bulletin&rft.date=2008-11-18&rft.volume=57&rft.issue=11&rft.spage=2385-2393&rft.epage=2385-2393&rft.eissn=1066-5285&rft.issn=1066-5285&rft.au=FEDOROV,%20Yuri%20V.&SHEPEL,%20N.%20E.&CHERNIKOVA,%20Ekaterina%20Yu.&FEDOROVA,%20Olga%20A.&GULAKOVA,%20Elena%20N.&rft.genre=article |
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