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Preparation, Crystal Structure and Caracterization of Inorganic-Organic Hybrid Perovskite [NH3-(CH2)10-NH3] ZnCl4

hal.structure.identifierLaboratoire de Physique des Matériaux et Modélisation des Systèmes [Meknès] [LP2MS]
dc.contributor.authorELMEBROUKI, Keltoum
hal.structure.identifierEcole Supérieur de Technologie [Meknès]
dc.contributor.authorKHECHOUBI, El Mostafa
hal.structure.identifierLaboratoire de Physique des Matériaux et Modélisation des Systèmes [Meknès] [LP2MS]
dc.contributor.authorKAÏBA, Abdellah
hal.structure.identifierLaboratoire de Physique des Matériaux et Modélisation des Systèmes [Meknès] [LP2MS]
dc.contributor.authorBELAARAJ, Abdesselam
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorMONDIEIG, Denise
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorNÉGRIER, Philippe
dc.date.issued2013-05-01
dc.identifier.issn2226-5724
dc.description.abstractEnA new perovskite like system [NH3-(CH2)10-NH3] ZnCl4, has been synthesized and characterized by single crystal X-ray diffraction, thermal analysis and infrared spectroscopic study. This compound crystallize in a triclinic space group P-1, with the unit cell parameters a=7.294(1), b=10.058(9) Å, c=12.812(1) Å, α = 90, 89(2), β = 101, 21(1), γ = 92, 40(3) and Z=2. The final R factor is 0,082. The structure of this compound might be described as layered with two parallel anionic and cationic layers. The first layer is composed by isolated distorted tetrahedral (ZnCl4)2- and the second layer of [NH3-(CH2)x-NH3]2+. Network hydrogen - bonding assures the cohesion between these layers and stabilizes the crystal. The structure shows the existence of a conformational disorder of the organic chains between " trans " and " twisted " states. The thermal analysis by DSC shows that the 2C10ZnCl4 perovskite presents reversible phase transition.
dc.language.isoen
dc.publisherAESS Publications
dc.rights.urihttp://creativecommons.org/licenses/by-nc/
dc.subject.enPerovskite structure
dc.subject.enMolecular composite
dc.subject.enX-ray diffraction
dc.subject.enCrystal structure
dc.subject.enphase transitions in layered systems
dc.title.enPreparation, Crystal Structure and Caracterization of Inorganic-Organic Hybrid Perovskite [NH3-(CH2)10-NH3] ZnCl4
dc.typeArticle de revue
dc.subject.halChimie/Cristallographie
bordeaux.journalJournal of Asian Scientific Research
bordeaux.page454-461
bordeaux.volume3
bordeaux.issue5
bordeaux.peerReviewedoui
hal.identifierhal-00843371
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00843371v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Asian%20Scientific%20Research&rft.date=2013-05-01&rft.volume=3&rft.issue=5&rft.spage=454-461&rft.epage=454-461&rft.eissn=2226-5724&rft.issn=2226-5724&rft.au=ELMEBROUKI,%20Keltoum&KHECHOUBI,%20El%20Mostafa&KA%C3%8FBA,%20Abdellah&BELAARAJ,%20Abdesselam&MONDIEIG,%20Denise&rft.genre=article


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