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Single crystal and magnetic structures of maricite-type AgMnVO4

hal.structure.identifierResearch Institute for Ubiquitous Energy Devices
dc.contributor.authorBEN YAHIA, Hamdi
hal.structure.identifierResearch Institute for Ubiquitous Energy Devices
dc.contributor.authorMASAHIRO, Shikano
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGAUDIN, Etienne
hal.structure.identifierBragg Institute
dc.contributor.authorMAXIM, Avdeev
hal.structure.identifierSchool of Chemistry, The University of Sydney
dc.contributor.authorD. LING, Chris
dc.date.issued2015
dc.identifier.issn0022-4596
dc.description.abstractEnSingle crystals of the ternary manganese vanadate AgMnVO4, were grown using AgVO3 flux. The structure was determined from single crystal X-ray diffraction data. The magnetic structure and properties of AgMnVO4 were characterized by magnetic susceptibility, specific heat, and low-temperature neutron powder diffraction measurements. AgMnVO4 crystallizes in the maricite-type structure with space group Pnma, a=9.5393(12), b=6.8132(9), c=5.3315(7) Å and Z=4. AgMnVO4 contains MnO4 chains made up of edge-sharing MnO6 octahedra, and these chains are interlinked by the VO4 and AgO4 tetrahedra. The specific heat measurements indicate a 3D-antiferromagnetic ordering at ~12.1 K and the neutron powder diffraction measurements at 5 K show that the Mn2+magnetic moments are antiferromagnetically coupled within the chains which are antiferromagnetically coupled to each other.
dc.language.isoen
dc.publisherElsevier
dc.subject.enVanadate
dc.subject.enFlux growth
dc.subject.enSingle crystal
dc.subject.enMagnetic structure
dc.title.enSingle crystal and magnetic structures of maricite-type AgMnVO4
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jssc.2014.09.017
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Solid State Chemistry
bordeaux.page306-310
bordeaux.volume221
bordeaux.peerReviewedoui
hal.identifierhal-01103989
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01103989v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Solid%20State%20Chemistry&rft.date=2015&rft.volume=221&rft.spage=306-310&rft.epage=306-310&rft.eissn=0022-4596&rft.issn=0022-4596&rft.au=BEN%20YAHIA,%20Hamdi&MASAHIRO,%20Shikano&GAUDIN,%20Etienne&MAXIM,%20Avdeev&D.%20LING,%20Chris&rft.genre=article


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