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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPOULON-QUINTIN, Angeline
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFAURE, Cyril
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorTEULÉ-GAY, Lionel
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMANAUD, Jean Pierre
dc.date.issued2015
dc.identifier.issn0169-4332
dc.description.abstractEnNano-crystalline diamond (NCD) films grown under negative biased substrates by chemical vapor deposition (CVD) are widely used as surface overlay coating onto cermet WC-Co cutting tools to get better performances. To improve the diamond adhesion to the cermet substrate, suitable multi-layer systems have been added. They are composed of a cobalt diffusion barrier close to the substrate (single and sequenced nitrides layers) coated with a nucleation extra layer to improve the nucleus density of diamond during CVD processing. For all systems, before and after diamond deposition, transmission electron microscopy (TEM) has been performed for a better understanding of the diffusion phenomena occurring at the interfaces and to evaluate the presence of graphitic species at the interface with the diamond. Innovative multilayer system dedicated to the regulation of cobalt diffusion coated with a bilayer system optimized for the carbon diffusion control, is shown as an efficient solution to significantly reduce the graphite layer formation at the interface with the diamond down to 10 nm thick and to increase the adhesion of NCD diamond layer as scratch-tests confirm.
dc.language.isoen
dc.publisherElsevier
dc.subject.enNitrides
dc.subject.enInterfaces
dc.subject.enDiffusion
dc.subject.enGraphite
dc.subject.enNano crystalline diamond
dc.subject.enMW-CVD
dc.title.enA multilayer innovative solution to improve the adhesion of nanocrystalline diamond coatings
dc.typeArticle de revue
dc.identifier.doi10.1016/j.apsusc.2015.01.050
dc.subject.halChimie/Matériaux
bordeaux.journalApplied Surface Science
bordeaux.page27-34
bordeaux.volume331
bordeaux.peerReviewedoui
hal.identifierhal-01113708
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01113708v1
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