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Alkynyl-functionalized imidazolium for "click" dendrimer functionalisation and palladium nanoparticle stabilization

hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorDERAEDT, Christophe
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorD'HALLUIN, Martin
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLESTURGEZ, Stéphanie
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorSALMON, Lionel
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGOGLIO, Graziella
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorRUIZ, Jaime
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorASTRUC, Didier
dc.date.issued2015
dc.identifier.issn1434-1948
dc.description.abstractEnFunctionalization of imidazolium salts (IMSs) that allow easy derivation of molecular or solid supports are called for in various applications. Here, the synthesis of an alkyne-containing IMS can be achieved in three steps from 2,4,6-trimethylaniline, and this IMS can be further successfully functionalized by using either Sonogashira or a “click” CuAAC reaction that was applied to dendritic IMS synthesis giving high yields. Applications are illustrated for Pd nanoparticle stabilization by the IMS dendrimer for Suzuki–Miyaura catalysis.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enDendrimers
dc.subject.enNanostructures
dc.subject.enClick chemistry
dc.subject.enHomogeneous catalysis
dc.subject.enPalladium
dc.title.enAlkynyl-functionalized imidazolium for "click" dendrimer functionalisation and palladium nanoparticle stabilization
dc.typeArticle de revue
dc.identifier.doi10.1002/ejic.201403045
dc.subject.halChimie/Matériaux
bordeaux.journalEuropean Journal of Inorganic Chemistry
bordeaux.page1345-1350
bordeaux.issue8
bordeaux.peerReviewedoui
hal.identifierhal-01131922
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01131922v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2015&rft.issue=8&rft.spage=1345-1350&rft.epage=1345-1350&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=DERAEDT,%20Christophe&D'HALLUIN,%20Martin&LESTURGEZ,%20St%C3%A9phanie&SALMON,%20Lionel&GOGLIO,%20Graziella&rft.genre=article


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