Stereochemistry for engineering spin crossover: structures and magnetic properties of a homochiral vs. racemic [Fe(N3O2)(CN)2] complex.
| hal.structure.identifier | Department of Chemistry | |
| hal.structure.identifier | School of Chemistry and Chemical Engineering | |
| dc.contributor.author | WANG, Qiang | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | VENNERI, Shari | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | ZARRABI, Niloofar | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | WANG, Hongfeng | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DESPLANCHES, Cédric | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| hal.structure.identifier | Department of Physics and Astronomy [Bellingham] | |
| dc.contributor.author | SEDA, Takele | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | PILKINGTON, Melanie | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 1477-9226 | |
| dc.description.abstractEn | The Schiff-base condensation of the R,R-(+)-diamine () with 2,6-diacetyl pyridine in the presence of FeII affords the macrocyclic complex [Fe(dpN3O2)(CN)2] () (dp = diphenyl) with ligand centred chirality comprising of a 1 : 1 mixture of LS 6- and HS 7-coordinate FeII centres. Variable temperature magnetic susceptibility and Mössbauer studies reveal that () undergoes an incomplete thermal SCO transition with a T1/2 = 250 K as well as a LIESST effect. In contrast its racemic counterpart () comprises of mostly LS FeII and exhibits no LIESST properties. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.title.en | Stereochemistry for engineering spin crossover: structures and magnetic properties of a homochiral vs. racemic [Fe(N3O2)(CN)2] complex. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c5dt00357a | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Dalton Transactions | |
| bordeaux.page | 6711-6714 | |
| bordeaux.volume | 44 | |
| bordeaux.issue | 15 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01139023 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01139023v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Dalton%20Transactions&rft.date=2015&rft.volume=44&rft.issue=15&rft.spage=6711-6714&rft.epage=6711-6714&rft.eissn=1477-9226&rft.issn=1477-9226&rft.au=WANG,%20Qiang&VENNERI,%20Shari&ZARRABI,%20Niloofar&WANG,%20Hongfeng&DESPLANCHES,%20C%C3%A9dric&rft.genre=article |
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