On the importance of ferromagnetic exchange between transition metals in field-free SMMs: examples of ring-shaped hetero-trimetallic [(LnNi2){W(CN)8}]2 compounds.
hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
dc.contributor.author | DHERS, Sébastien | |
hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
dc.contributor.author | COSTES, Jean- Pierre | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GUIONNEAU, Philippe | |
hal.structure.identifier | Magnétisme et Supraconductivité [NEEL - MagSup] | |
dc.contributor.author | PAULSEN, Carley | |
hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
dc.contributor.author | VENDIER, Laure | |
hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
dc.contributor.author | SUTTER, Jean-Pascal | |
dc.date.issued | 2015 | |
dc.identifier.issn | 1359-7345 | |
dc.description.abstractEn | Rare cases of genuine (i.e. field-free) SMM have been found for mixed 3d-4f-5d ring-shaped compounds with Tb(iii) (Ueff/kB = 23.0 K) or Dy(iii) (Ueff/kB = 26.4 K). The ferromagnetic interactions between the transition metals are shown to play an essential role in this feature. | |
dc.description.sponsorship | / - ANR-09-BLAN-0054 | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.title.en | On the importance of ferromagnetic exchange between transition metals in field-free SMMs: examples of ring-shaped hetero-trimetallic [(LnNi2){W(CN)8}]2 compounds. | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/c5cc01743b | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Chemical Communications | |
bordeaux.page | 7875-7878 | |
bordeaux.volume | 51 | |
bordeaux.issue | 37 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01149702 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01149702v1 | |
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