Linking magnetic MII-[MV(CN)8] chains into 2D inorganic-organic hybrid materials
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | STEFAŃCZYK, Olaf | |
hal.structure.identifier | M. Smoluchowski Institute of Physics | |
dc.contributor.author | MAJCHER, Anna M. | |
hal.structure.identifier | M. Smoluchowski Institute of Physics | |
dc.contributor.author | RAMS, Michał | |
hal.structure.identifier | Faculty of Chemistry | |
dc.contributor.author | NITEK, Wojciech | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | MATHONIÈRE, Corine | |
hal.structure.identifier | Faculty of Chemistry | |
dc.contributor.author | SIEKLUCKA, Barbara | |
dc.date.issued | 2015 | |
dc.description.abstractEn | Three isostructural 2D inorganic–organic hybrid MII–[MV(CN)8]3− materials with pyrazine (pyz) incorporated as a short organic linker between 3,2-chain motifs: [MII(pyz)(DMF)3]2[MII(DMF)4][MV(CN)8]2 (where MII/MV is Co/W in 1; Cu/W in 2; and Cu/Mo in 3), were constructed from the combinations formed in situ by MII–pyrazine (MII = Co, Cu) assemblies with cyanide building blocks [MV(CN)8]3− (MV = Mo, W). The unprecedented architecture of 1–3 reveals no crystallization solvent molecules and propagation of pyrazine bridges in a perpendicular direction, contrary to the previously reported compound [CuII(4,4′-bpy)(DMF)]2[CuII(4,4′-bpy)(DMF)2][WV(CN)8]2·2DMF·2H2O with 4,4′-bipyridine bridges. Magnetic studies of 1–3 reveal the presence of overall ferromagnetic interactions in the cyanido-bridged MII–WV pairs and weak antiferromagnetic interactions transferred through the MII–pyz–MII linkages. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.title.en | Linking magnetic MII-[MV(CN)8] chains into 2D inorganic-organic hybrid materials | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/C5CE00414D | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | CrystEngComm | |
bordeaux.page | 4533-4539 | |
bordeaux.volume | 17 | |
bordeaux.issue | 24 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01211570 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01211570v1 | |
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