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Linking magnetic MII-[MV(CN)8] chains into 2D inorganic-organic hybrid materials

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSTEFAŃCZYK, Olaf
hal.structure.identifierM. Smoluchowski Institute of Physics
dc.contributor.authorMAJCHER, Anna M.
hal.structure.identifierM. Smoluchowski Institute of Physics
dc.contributor.authorRAMS, Michał
hal.structure.identifierFaculty of Chemistry
dc.contributor.authorNITEK, Wojciech
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierFaculty of Chemistry
dc.contributor.authorSIEKLUCKA, Barbara
dc.date.issued2015
dc.description.abstractEnThree isostructural 2D inorganic–organic hybrid MII–[MV(CN)8]3− materials with pyrazine (pyz) incorporated as a short organic linker between 3,2-chain motifs: [MII(pyz)(DMF)3]2[MII(DMF)4][MV(CN)8]2 (where MII/MV is Co/W in 1; Cu/W in 2; and Cu/Mo in 3), were constructed from the combinations formed in situ by MII–pyrazine (MII = Co, Cu) assemblies with cyanide building blocks [MV(CN)8]3− (MV = Mo, W). The unprecedented architecture of 1–3 reveals no crystallization solvent molecules and propagation of pyrazine bridges in a perpendicular direction, contrary to the previously reported compound [CuII(4,4′-bpy)(DMF)]2[CuII(4,4′-bpy)(DMF)2][WV(CN)8]2·2DMF·2H2O with 4,4′-bipyridine bridges. Magnetic studies of 1–3 reveal the presence of overall ferromagnetic interactions in the cyanido-bridged MII–WV pairs and weak antiferromagnetic interactions transferred through the MII–pyz–MII linkages.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enLinking magnetic MII-[MV(CN)8] chains into 2D inorganic-organic hybrid materials
dc.typeArticle de revue
dc.identifier.doi10.1039/C5CE00414D
dc.subject.halChimie/Matériaux
bordeaux.journalCrystEngComm
bordeaux.page4533-4539
bordeaux.volume17
bordeaux.issue24
bordeaux.peerReviewedoui
hal.identifierhal-01211570
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01211570v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=CrystEngComm&rft.date=2015&rft.volume=17&rft.issue=24&rft.spage=4533-4539&rft.epage=4533-4539&rft.au=STEFA%C5%83CZYK,%20Olaf&MAJCHER,%20Anna%20M.&RAMS,%20Micha%C5%82&NITEK,%20Wojciech&MATHONI%C3%88RE,%20Corine&rft.genre=article


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