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A ZrNiAl related high-pressure modification fo CeRuSn
hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
dc.contributor.author | NIEHAUS, Oliver | |
hal.structure.identifier | Institut für Allgemeine, Anorganische und Theoretische Chemie | |
dc.contributor.author | HEYMANN, Gunter | |
hal.structure.identifier | Institut für Allgemeine, Anorganische und Theoretische Chemie | |
dc.contributor.author | HUPPERTZ, Hubert | |
hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
dc.contributor.author | RODEWALD, Ute Ch. | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHEVALIER, Bernard | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | MATAR, Samir F. | |
hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
dc.contributor.author | HOFFMANN, Rolf-Dieter | |
hal.structure.identifier | Institut für Anorganische und Analytische Chemie | |
dc.contributor.author | PÖTTGEN, Rainer | |
dc.date.issued | 2016 | |
dc.identifier.issn | 1477-9226 | |
dc.description.abstractEn | Monoclinic CeRuSn with its own structure type transforms to a high-pressure modification at 11.5 GPa and 1470 K (1000 t press, Walker type module). The structure of the high-pressure phase was refined from X-ray single crystal diffractometer data at room temperature. The HP-CeRuSn subcell structure adopts the ZrNiAl type: P[6 with combining macron]2m, a = 751.4(3) and c = 394.6(2) pm, wR2 = 0.0787, 310 F2 values and 15 variables. The Ru2 atoms within the Sn6 trigonal prisms show a strongly enhanced U33 parameter. Weak satellite reflections indicate a commensurate modulation: (3 + 1)D superspace group P31m(1/3,1/3,γ)000, a = 751.4(3) and c = 394.6(2) pm, γ = −1/3, wR2 = 0.0786, 1584 F2 values, 32 variables for the main reflections and wR2 = 0.3757 for the satellites of 1st order. A description of this new superstructure variant of the ZrNiAl type is possible in a transformed 3D supercell with the space group R3m and Z = 9. The driving force for formation of the modulation is strengthening of Ru–Sn bonding within the comparatively large Ru@Sn6 trigonal prisms. Electronic structure calculations point to an almost depleted Ce 4f shell. This is substantiated by temperature-dependent magnetic susceptibility data. Fitting of the data within the interconfiguration fluctuation model (ICF) resulted in cerium valences of 3.41 at 10 K and 3.31 at 350 K. Temperature dependent specific heat data underline the absence of magnetic ordering. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.title.en | A ZrNiAl related high-pressure modification fo CeRuSn | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/C6DT02294D | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Dalton Transactions | |
bordeaux.page | 14216-14229 | |
bordeaux.volume | 45 | |
bordeaux.issue | 36 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01367775 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01367775v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Dalton%20Transactions&rft.date=2016&rft.volume=45&rft.issue=36&rft.spage=14216-14229&rft.epage=14216-14229&rft.eissn=1477-9226&rft.issn=1477-9226&rft.au=NIEHAUS,%20Oliver&HEYMANN,%20Gunter&HUPPERTZ,%20Hubert&RODEWALD,%20Ute%20Ch.&CHEVALIER,%20Bernard&rft.genre=article |
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