Interplay between kinetically slow thermal spin-crossover and metastable high-spin state relaxation in an iron(II) complex with similar T1/2 and T(LIESST)
| hal.structure.identifier | Chemical Crystallography Group, Chemistry Department | |
| dc.contributor.author | MONEY, Victoria A. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CARBONERA, Chiara | |
| hal.structure.identifier | School of Chemistry [Leeds] | |
| dc.contributor.author | ELHAÏK, Jérôme | |
| hal.structure.identifier | School of Chemistry [Leeds] | |
| dc.contributor.author | HALCROW, Malcolm A. | |
| hal.structure.identifier | Chemical Crystallography Group, Chemistry Department | |
| dc.contributor.author | HOWARD, Judith A. K. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| dc.date.issued | 2007 | |
| dc.identifier.issn | 0947-6539 | |
| dc.description.abstractEn | his paper describes the first material to show the well-known light-induced excited spin-state trapping (LIESST) effect, the metastable excited state of which relaxes at a temperature approaching its thermal spin-crossover. Cooling polycrystalline [FeL2][BF4]2x H2O (L=2,6-bis{3-methylpyrazol-1-yl}pyridine; x=0-1/3) at 1 K min-1 leads to a cooperative spin transition, taking place in two steps centered at 147 and 105 K, that is only 54 % complete by magnetic susceptibility... | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Coordination chemistry | |
| dc.subject.en | Iron | |
| dc.subject.en | Magnetic properties | |
| dc.subject.en | Photomagnetism | |
| dc.subject.en | Spin crossover | |
| dc.title.en | Interplay between kinetically slow thermal spin-crossover and metastable high-spin state relaxation in an iron(II) complex with similar T1/2 and T(LIESST) | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/chem.200601312 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Chemistry - A European Journal | |
| bordeaux.page | 5503-5514 | |
| bordeaux.volume | 13 | |
| bordeaux.issue | 19 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00160388 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00160388v1 | |
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