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A novel cyano-bridged pentanuclear complex: [{Mn3(MAC)3(H2O)2}{Fe(CN)6}2]·6H2O·2CH3OH—synthesis, crystal structure and magnetic properties (MAC=pentaaza macrocyclic ligand)
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | TANASE, Stefania | |
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | ANDRUH, Marius | |
| hal.structure.identifier | Coordination Chemistry Laboratory | |
| dc.contributor.author | STANICA, Nicolae | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | ROMBAUT, Guillaume | |
| hal.structure.identifier | Laboratoire de Chimie du solide et inorganique moléculaire [LCSIM] | |
| dc.contributor.author | GOLHEN, Stéphane | |
| hal.structure.identifier | Organométalliques: Matériaux et Catalyse | |
| dc.contributor.author | OUAHAB, Lahcène | |
| dc.date.issued | 2003 | |
| dc.identifier.issn | 0277-5387 | |
| dc.description.abstractEn | The reaction between K3[Fe(CN)6] and [Mn(MAC)(H2O)2]Cl2·4H2O (MAC=2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene) in a water/methanol mixture affords a pentanuclear complex with the formula [{Mn3(MAC)3(H2O)2}{Fe(CN)6}2]·6H2O·2CH3OH (1), whose crystal structure has been solved. It consists of discrete [MnIIFeIIIMnIIFeIIIMnII] entities. The three {Mn(MAC}2+ moieties are connected by two [Fe(CN)6]3− anions, each one involving two cis cyano bridging groups... | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Crystal structure | |
| dc.subject.en | Cyano-bridged complexes | |
| dc.subject.en | Manganese complexes | |
| dc.subject.en | Iron complexes | |
| dc.subject.en | Macrocyclic ligands | |
| dc.subject.en | Magnetic properties | |
| dc.title.en | A novel cyano-bridged pentanuclear complex: [{Mn3(MAC)3(H2O)2}{Fe(CN)6}2]·6H2O·2CH3OH—synthesis, crystal structure and magnetic properties (MAC=pentaaza macrocyclic ligand) | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/S0277-5387(03)00106-2 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Polyhedron | |
| bordeaux.page | 1315-1320 | |
| bordeaux.volume | 22 | |
| bordeaux.issue | 10 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00163422 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00163422v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polyhedron&rft.date=2003&rft.volume=22&rft.issue=10&rft.spage=1315-1320&rft.epage=1315-1320&rft.eissn=0277-5387&rft.issn=0277-5387&rft.au=TANASE,%20Stefania&ANDRUH,%20Marius&STANICA,%20Nicolae&MATHONI%C3%88RE,%20Corine&ROMBAUT,%20Guillaume&rft.genre=article |
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