High spin to low spin relaxation regime change in a multistep 3D spin-crossover material
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHASTANET, Guillaume | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | SCIORTINO, Natasha | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | NEVILLE, Suzanne | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | KEPERT, Cameron | |
| dc.date.issued | 2018 | |
| dc.identifier.issn | 1434-1948 | |
| dc.description.abstractEn | The paper reports the study of the photoinduced high spin (HS) state lifetime in a multistep spin crossover compound. Despite the pronounced three-step transition of the [Fe(dpsme)Pt(CN)4]·2/3dpsme·xEtOH·yH2O {dpsme = 4,4′-di(pyridylthio)methane; EtOH = ethanol} 3D compound, neither the T(LIESST) nor the relaxation kinetics exhibits stepwise features. From the detailed investigation (experiments and simulations) of these relaxations and the observation of the light-induced thermal hysteresis, a phase transition around 58 K is suspected. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.title.en | High spin to low spin relaxation regime change in a multistep 3D spin-crossover material | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/ejic.201701127 | |
| dc.subject.hal | Chimie/Matériaux | |
| dc.subject.hal | Chimie/Chimie de coordination | |
| bordeaux.journal | European Journal of Inorganic Chemistry | |
| bordeaux.page | 314-319 | |
| bordeaux.volume | 2018 | |
| bordeaux.issue | 3-4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01696992 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01696992v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2018&rft.volume=2018&rft.issue=3-4&rft.spage=314-319&rft.epage=314-319&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=CHASTANET,%20Guillaume&SCIORTINO,%20Natasha&NEVILLE,%20Suzanne&KEPERT,%20Cameron&rft.genre=article |
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