Afficher la notice abrégée

High spin to low spin relaxation regime change in a multistep 3D spin-crossover material

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASTANET, Guillaume
hal.structure.identifierSchool of Chemistry
dc.contributor.authorSCIORTINO, Natasha
hal.structure.identifierSchool of Chemistry
dc.contributor.authorNEVILLE, Suzanne
hal.structure.identifierSchool of Chemistry
dc.contributor.authorKEPERT, Cameron
dc.date.issued2018
dc.identifier.issn1434-1948
dc.description.abstractEnThe paper reports the study of the photoinduced high spin (HS) state lifetime in a multistep spin crossover compound. Despite the pronounced three-step transition of the [Fe(dpsme)Pt(CN)4]·2/3dpsme·xEtOH·yH2O {dpsme = 4,4′-di(pyridylthio)methane; EtOH = ethanol} 3D compound, neither the T(LIESST) nor the relaxation kinetics exhibits stepwise features. From the detailed investigation (experiments and simulations) of these relaxations and the observation of the light-induced thermal hysteresis, a phase transition around 58 K is suspected.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enHigh spin to low spin relaxation regime change in a multistep 3D spin-crossover material
dc.typeArticle de revue
dc.identifier.doi10.1002/ejic.201701127
dc.subject.halChimie/Matériaux
dc.subject.halChimie/Chimie de coordination
bordeaux.journalEuropean Journal of Inorganic Chemistry
bordeaux.page314-319
bordeaux.volume2018
bordeaux.issue3-4
bordeaux.peerReviewedoui
hal.identifierhal-01696992
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01696992v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2018&rft.volume=2018&rft.issue=3-4&rft.spage=314-319&rft.epage=314-319&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=CHASTANET,%20Guillaume&SCIORTINO,%20Natasha&NEVILLE,%20Suzanne&KEPERT,%20Cameron&rft.genre=article


Fichier(s) constituant ce document

FichiersTailleFormatVue

Il n'y a pas de fichiers associés à ce document.

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée