High spin to low spin relaxation regime change in a multistep 3D spin-crossover material
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHASTANET, Guillaume | |
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | SCIORTINO, Natasha | |
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | NEVILLE, Suzanne | |
hal.structure.identifier | School of Chemistry | |
dc.contributor.author | KEPERT, Cameron | |
dc.date.issued | 2018 | |
dc.identifier.issn | 1434-1948 | |
dc.description.abstractEn | The paper reports the study of the photoinduced high spin (HS) state lifetime in a multistep spin crossover compound. Despite the pronounced three-step transition of the [Fe(dpsme)Pt(CN)4]·2/3dpsme·xEtOH·yH2O {dpsme = 4,4′-di(pyridylthio)methane; EtOH = ethanol} 3D compound, neither the T(LIESST) nor the relaxation kinetics exhibits stepwise features. From the detailed investigation (experiments and simulations) of these relaxations and the observation of the light-induced thermal hysteresis, a phase transition around 58 K is suspected. | |
dc.language.iso | en | |
dc.publisher | Wiley-VCH Verlag | |
dc.title.en | High spin to low spin relaxation regime change in a multistep 3D spin-crossover material | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/ejic.201701127 | |
dc.subject.hal | Chimie/Matériaux | |
dc.subject.hal | Chimie/Chimie de coordination | |
bordeaux.journal | European Journal of Inorganic Chemistry | |
bordeaux.page | 314-319 | |
bordeaux.volume | 2018 | |
bordeaux.issue | 3-4 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01696992 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01696992v1 | |
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