Transient absorption spectroscopy of the [Fe(2 CH3-phen)3]2+ complex: Study of the high spin ↔ low spin relaxation of an isolated iron(II) complex
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | GALLÉ, Geoffrey | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | JONUSAUSKAS, Gediminas | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | TONDUSSON, Marc | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MAURIAC, Cindy | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LETARD, Jean-François | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | FREYSZ, Eric | |
| dc.date.created | 2012-09-14 | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 0009-2614 | |
| dc.description.abstractEn | We report on the light induced spin crossover dynamics of [Fe(2 CH3-phen)3]2+ complex in solution. The excitation of the complex by pulses centered at λ = 500 nm along the metal to ligand charge transfer absorption band indicates a selective excitation of the LS state. The excitation of the complex by pulses centered at λ = 330 nm or λ = 335 nm reveals an increase of the LS state population and a photo-bleaching of the HS state population that is associated to a transient photo-dissociation. A method that makes it possible to deduce the kinetics of both the HS → LS state and LS → HS state is proposed. | |
| dc.description.sponsorship | / - ANR-09-BLAN-0212 | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/ | |
| dc.title.en | Transient absorption spectroscopy of the [Fe(2 CH3-phen)3]2+ complex: Study of the high spin ↔ low spin relaxation of an isolated iron(II) complex | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/J.CPLETT.2012.11.034 | |
| dc.subject.hal | Chimie/Chimie théorique et/ou physique | |
| dc.subject.hal | Chimie/Chimie de coordination | |
| bordeaux.journal | Chemical Physics Letters | |
| bordeaux.page | 82-88 | |
| bordeaux.volume | 556 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00788820 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00788820v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Physics%20Letters&rft.date=2013&rft.volume=556&rft.spage=82-88&rft.epage=82-88&rft.eissn=0009-2614&rft.issn=0009-2614&rft.au=GALL%C3%89,%20Geoffrey&JONUSAUSKAS,%20Gediminas&TONDUSSON,%20Marc&MAURIAC,%20Cindy&LETARD,%20Jean-Fran%C3%A7ois&rft.genre=article |
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