Crystal structure, Mössbauer spectroscopy and magnetic properties of a new potassium iron oxyphosphate K11Fe15(PO4)18O related to the Langbeinite-like compounds
| hal.structure.identifier | Laboratoire de Chimie Structurale des Matériaux, Département de Chimie | |
| dc.contributor.author | LAJMI, Besma | |
| hal.structure.identifier | Laboratoire de Chimie Structurale des Matériaux, Département de Chimie | |
| dc.contributor.author | HIDOURI, Mourad | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | WATTIAUX, Alain | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | FOURNÈS, Léopold | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DARRIET, Jacques | |
| hal.structure.identifier | Laboratoire de Chimie Structurale des Matériaux, Département de Chimie | |
| dc.contributor.author | BEN AMARA, Mongi | |
| dc.date.issued | 2003 | |
| dc.identifier.issn | 0925-8388 | |
| dc.description.abstractEn | new potassium iron phosphate K11Fe15(PO4)18O has been synthesized by the flux method and characterized by single-crystal X-ray diffraction. The compound crystallizes in the cubic system with the space group P213 and the cell parameter a=9.917(2) Å. The unit cell contains one formula unit K7.33Fe10(PO4)12O0.66. The structure is closely related to that of the Langbeinite-like compounds, the main difference being the existence of a four-coordinated iron atom in the structure of the oxyphosphate. K11Fe15(PO4)18O adopts a complex three-dimensional network involving corner- and edge-linkage between iron polyhedra, and corner-sharing between phosphorus tetrahedra and iron polyhedra... | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Transition metal compounds | |
| dc.subject.en | Crystal structure | |
| dc.subject.en | Mössbauer spectroscopy | |
| dc.subject.en | Magnetic measurements | |
| dc.title.en | Crystal structure, Mössbauer spectroscopy and magnetic properties of a new potassium iron oxyphosphate K11Fe15(PO4)18O related to the Langbeinite-like compounds | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/S0925-8388(03)00412-2 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Alloys and Compounds | |
| bordeaux.page | 77-83 | |
| bordeaux.volume | 361 | |
| bordeaux.issue | 1-2 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00175001 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00175001v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Alloys%20and%20Compounds&rft.date=2003&rft.volume=361&rft.issue=1-2&rft.spage=77-83&rft.epage=77-83&rft.eissn=0925-8388&rft.issn=0925-8388&rft.au=LAJMI,%20Besma&HIDOURI,%20Mourad&WATTIAUX,%20Alain&FOURN%C3%88S,%20L%C3%A9opold&DARRIET,%20Jacques&rft.genre=article |
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