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Structure-property correlation over five phases and four transitions in Pb5Al3F19
| hal.structure.identifier | Physics Department | |
| dc.contributor.author | ABRAHAMS, S. C. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | RAVEZ, Jean | |
| hal.structure.identifier | Lehr und Forschungsbereich für Röntgen und Neutronenbeugung | |
| dc.contributor.author | RITTER, H. | |
| hal.structure.identifier | Lehr und Forschungsbereich für Röntgen und Neutronenbeugung | |
| dc.contributor.author | IHRINGER, J. | |
| dc.date.issued | 2003 | |
| dc.identifier.issn | 0108-7681 | |
| dc.description.abstractEn | The calorimetric and dielectric properties of Pb5Al3F19 in the five phases stable under ambient pressure are correlated with structure for fuller characterization of each phase. The first-order transition between ferroelectric phase V and antiferroelectric phase IV at TV,IV = 260 (5) K exhibits a thermal hysteresis of 135 (5) K on heating, with a maximum atomic displacement [Delta](xyz)max = 1.21 (6) Å; the transition from phase IV to ferroelastic phase III at 315 (5) K is also first order but with a thermal hysteresis of 10 (5) K... | |
| dc.language.iso | en | |
| dc.publisher | International Union of Crystallography | |
| dc.subject.en | Dielectric properties | |
| dc.subject.en | Structure property correlation | |
| dc.subject.en | Phase transitions | |
| dc.subject.en | Calorimetry | |
| dc.subject.en | Dielectric properties. | |
| dc.title.en | Structure-property correlation over five phases and four transitions in Pb5Al3F19 | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1107/S0108768103011509 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Acta Crystallographica Section B : Structural Science [1968-2013] | |
| bordeaux.page | 557-574 | |
| bordeaux.volume | 59 | |
| bordeaux.issue | 5 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00177103 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00177103v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Acta%20Crystallographica%20Section%20B%20:%20Structural%20Science%20%5B1968-2013%5D&rft.date=2003&rft.volume=59&rft.issue=5&rft.spage=557-574&rft.epage=557-574&rft.eissn=0108-7681&rft.issn=0108-7681&rft.au=ABRAHAMS,%20S.%20C.&RAVEZ,%20Jean&RITTER,%20H.&IHRINGER,%20J.&rft.genre=article |
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