Mostrar el registro sencillo del ítem
Crystal structure and identification of a pyrimido[6,1-b][1,3]oxazin-6-one derivative from the reaction of acrolein with 5-(phenoxymethyl)-2-amino-2-oxazoline
hal.structure.identifier | Acides Nucléiques : Régulations Naturelle et Artificielle [ARNA] | |
dc.contributor.author | GUILLON, Jean | |
hal.structure.identifier | Acides Nucléiques : Régulations Naturelle et Artificielle [ARNA] | |
dc.contributor.author | RUBIO, Sandra | |
hal.structure.identifier | Acides Nucléiques : Régulations Naturelle et Artificielle [ARNA] | |
dc.contributor.author | SAVRIMOUTOU, Solène | |
hal.structure.identifier | Acides Nucléiques : Régulations Naturelle et Artificielle [ARNA] | |
dc.contributor.author | HALLÉ, François | |
hal.structure.identifier | Acides Nucléiques : Régulations Naturelle et Artificielle [ARNA] | |
dc.contributor.author | MOREAU, Stéphane | |
hal.structure.identifier | Agents infectieux, résistance et chimiothérapie - UR UPJV 4294 [AGIR ] | |
dc.contributor.author | SONNET, Pascal | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | MARCHIVIE, Mathieu | |
dc.date.issued | 2018-11 | |
dc.identifier.issn | 1631-0748 | |
dc.description.abstractEn | The X-ray crystal structure of 2-(4,5-dihydro-5-phenoxymethyl-1,3-oxazol-2-ylamino)-7-(2-hydroxy-3-phenoxypropyl)hexahydro-2H,6H-pyrimido[6,1-b][1,3]oxazin-6-one (1), a structure of adduct formed by the reaction of 5-(phenoxymethyl)-2-amino-2-oxazoline and acrolein, has been established. The present work deals with the structural identification of the adduct 1 and presents a plausible mechanism for its formation. It crystallizes in the monoclinic space group P21/c with cell parameters a = 21.3337 (10) Å, b = 11.3712 (7) Å, c = 10.4936 (7) Å, β = 103.041 (3), V = 2480.0 (3) Å3, Z = 4. C26H32N4O6, Dc = 1.330 g/cm3, μ (Cu Kα) = 1.5418 Å, S = 1.188, F (000) = 1056, R = 0.0501, and wR = 0.1584. | |
dc.language.iso | en | |
dc.publisher | Académie des sciences (Paris) | |
dc.subject.en | Pyrimido[6 | |
dc.subject.en | 1-b][1 | |
dc.subject.en | 3]oxazin-6-one | |
dc.subject.en | 2-Amino-2-oxazoline | |
dc.subject.en | Michael reaction | |
dc.subject.en | X-ray crystal structure | |
dc.title.en | Crystal structure and identification of a pyrimido[6,1-b][1,3]oxazin-6-one derivative from the reaction of acrolein with 5-(phenoxymethyl)-2-amino-2-oxazoline | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.crci.2018.09.013 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Comptes Rendus. Chimie | |
bordeaux.page | 987-992 | |
bordeaux.volume | 21 | |
bordeaux.issue | 11 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01922305 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01922305v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Comptes%20Rendus.%20Chimie&rft.date=2018-11&rft.volume=21&rft.issue=11&rft.spage=987-992&rft.epage=987-992&rft.eissn=1631-0748&rft.issn=1631-0748&rft.au=GUILLON,%20Jean&RUBIO,%20Sandra&SAVRIMOUTOU,%20Sol%C3%A8ne&HALL%C3%89,%20Fran%C3%A7ois&MOREAU,%20St%C3%A9phane&rft.genre=article |
Archivos en el ítem
Archivos | Tamaño | Formato | Ver |
---|---|---|---|
No hay archivos asociados a este ítem. |