[Mn(MAC){μ1,5-N(CN)2}](PF6): a new one-dimensional coordination polymer with μ1,5-dicyanamido bridges (MAC=pentaaza macrocyclic ligand)—synthesis, crystal structure and magnetic properties
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | PARASCHIV, Carmen | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | SUTTER, Jean-Pascal | |
| hal.structure.identifier | Fakultät für Chemie [Universität Bielefeld] | |
| dc.contributor.author | SCHMIDTMANN, Marc | |
| hal.structure.identifier | Fakultät für Chemie [Universität Bielefeld] | |
| dc.contributor.author | MÜLLER, Achim | |
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | ANDRUH, Marius | |
| dc.date.issued | 2003 | |
| dc.identifier.issn | 0277-5387 | |
| dc.description.abstractEn | The dicyanamido-bridged manganese(II) compound, [Mn(MAC){μ1,5-N(CN)2}](PF6), (1), has been obtained by reacting [Mn(MAC)(H2O)2]Cl2·4H2O with NaN(CN)2 and NaPF6 in a 1:1:1 molar ratio (MAC=2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene). The structure consists of [Mn(MAC){μ1,5-N(CN)2}]n n+ infinite chains and uncoordinated PF6 − ions. The manganese ions display a pentagonal-bipyramidal geometry, with the macrocyclic ligand forming the equatorial plane. The {Mn(MAC)} units are connected through μ1,5-dicyanamido bridges (both nitrile nitrogens coordinated). The cryomagnetic investigation of 1 reveals a very weak exchange interaction between the manganese(II) ions within the chain (J=−0.49 cm−1). | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Crystal structures | |
| dc.subject.en | Dicyanamido-bridged complexes | |
| dc.subject.en | Manganese complexes | |
| dc.subject.en | Macrocyclic ligands | |
| dc.subject.en | Magnetic properties | |
| dc.title.en | [Mn(MAC){μ1,5-N(CN)2}](PF6): a new one-dimensional coordination polymer with μ1,5-dicyanamido bridges (MAC=pentaaza macrocyclic ligand)—synthesis, crystal structure and magnetic properties | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/S0277-5387(03)00283-3 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Polyhedron | |
| bordeaux.page | 1611-1615 | |
| bordeaux.volume | 22 | |
| bordeaux.issue | 12 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00199780 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00199780v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Polyhedron&rft.date=2003&rft.volume=22&rft.issue=12&rft.spage=1611-1615&rft.epage=1611-1615&rft.eissn=0277-5387&rft.issn=0277-5387&rft.au=PARASCHIV,%20Carmen&SUTTER,%20Jean-Pascal&SCHMIDTMANN,%20Marc&M%C3%9CLLER,%20Achim&ANDRUH,%20Marius&rft.genre=article |
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