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Investigation of the Na2O/Ag2O ratio on the synthesis conditions and properties of the 80TeO2–10ZnO–[(10−x)Na2O–xAg2O] glasses

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierLaboratoire Interdisciplinaire Carnot de Bourgogne [ICB]
dc.contributor.authorBOIRUCHON, David
hal.structure.identifierLaboratoire Interdisciplinaire Carnot de Bourgogne [ICB]
dc.contributor.authorDÉSÉVÉDAVY, Frédéric
hal.structure.identifierIRCER - Axe 3 : organisation structurale multiéchelle des matériaux [IRCER-AXE3]
dc.contributor.authorCHENU, Sébastien
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSTRUTYNSKI, Clément
hal.structure.identifierLaboratoire Interdisciplinaire Carnot de Bourgogne [ICB]
dc.contributor.authorSMEKTALA, Frédéric
hal.structure.identifierLaboratoire Interdisciplinaire Carnot de Bourgogne [ICB]
dc.contributor.authorGADRET, Grégory
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorDUSSAUZE, Marc
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorJUBERA, Veronique
hal.structure.identifierCentre d'optique, photonique et laser
dc.contributor.authorMESSADDEQ, Younès
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARDINAL, Thierry
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDANTO, Sylvain
dc.date.issued2019
dc.identifier.issn0022-3093
dc.description.abstractEnProperties of the tellurite glasses 80TeO2–10ZnO–[(10−x)Na2O–xAg2O] are investigated as a function of the substitution ratio x between Na2O and Ag2O. One observe that the variation of glass transition temperature decreases monotonously with x and that surface crystallization mechanism is favored. The assignment of the Raman bands and their relation with the underlying glass structure is discussed. While both Na2O and Ag2O oxides act as glass network modifiers, their progressive equimolar substitution does not lead to a meaningful evolution in the structure of the TZ[Na10-xAgx] glass. The refractive index and the cut-off wavelength are found to increase with x. The compositional and wavelength dependence of refractive indices, cut-off wavelength and optical band gap energy is discussed in terms of changes brought about by Na2O/Ag2O substitution in the glass network. Finally, it is shown that interaction between the platinum crucible and the glass melt increases with the silver content in the glass
dc.description.sponsorshipInitiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003
dc.language.isoen
dc.publisherElsevier
dc.subject.enSilver
dc.subject.enTellurite
dc.subject.enGlass
dc.subject.enPlatinum
dc.title.enInvestigation of the Na2O/Ag2O ratio on the synthesis conditions and properties of the 80TeO2–10ZnO–[(10−x)Na2O–xAg2O] glasses
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jnoncrysol.2019.119691
dc.subject.halChimie/Matériaux
dc.description.sponsorshipEuropeCentre for functional and surface-functionalized glasses
bordeaux.journalJournal of Non-Crystalline Solids
bordeaux.page119691 (8 p.)
bordeaux.volume525
bordeaux.peerReviewedoui
hal.identifierhal-02325521
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02325521v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Non-Crystalline%20Solids&rft.date=2019&rft.volume=525&rft.spage=119691%20(8%20p.)&rft.epage=119691%20(8%20p.)&rft.eissn=0022-3093&rft.issn=0022-3093&rft.au=BOIRUCHON,%20David&D%C3%89S%C3%89V%C3%89DAVY,%20Fr%C3%A9d%C3%A9ric&CHENU,%20S%C3%A9bastien&STRUTYNSKI,%20Cl%C3%A9ment&SMEKTALA,%20Fr%C3%A9d%C3%A9ric&rft.genre=article


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