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Electrochemical ageing study of mixed lanthanum/praseodymium nickelates La2-PrNiO4+δ as oxygen electrodes for solid oxide fuel or electrolysis cells

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVIBHU, Vaibhav
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFLURA, Aurelien
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROUGIER, Aline
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorNICOLLET, Clément
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFOURCADE, Sébastien
hal.structure.identifierCentre de microcaractérisation Raimond Castaing [Centre Castaing]
dc.contributor.authorHUNGRÍA, Teresa
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGRENIER, Jean-Claude
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBASSAT, Jean-Marc.
dc.date.issued2020
dc.identifier.issn2095-4956
dc.description.abstractEnThe chemical and electrochemical stability of lanthanide nickelates La2NiO4+δ (LNO), Pr2NiO4+δ (PNO) and their mixed compounds La2-xPrxNiO4+δ (LPNOs) with x = 0.5, 1 or 1.5 is reported. The aim is to promote these materials as efficient electrodes for solid oxide fuel cell (SOFC) and/or solid oxide electrolysis cell (SOEC). La2NiO4+δ and La1.5Pr0.5NiO4+δ compounds are chemically very stable as powders over one month in the temperature range 600 − 800°C, while the other materials rich in praseodymium progressively decompose into various perovskite-deriving components with additional Pr6O11. Despite their uneven properties, all these materials are quite efficient and sustainable as electrodes on top of gadolinium doped ceria (GDCBL) // yttrium doped zirconia (8YSZ) electrolyte, for one month at 700°C without polarization. Under polarization (300 mA·cm−2), the electrochemical performances of LNO, PNO and La1.5Pr0.5NiO4+δ (LP5NO) quickly degrade in SOFC mode, i.e. for the oxygen reduction reaction, while they show durability in SOEC mode, i.e. for the oxide oxidation reaction.
dc.description.sponsorshipPerformance Et Robustesse pour les cellules d'Electrolyse haute température de Nouvelle génération - ANR-11-PRGE-0016
dc.description.sponsorshipEleCtrOdes architecturées pour la Réalisation d'Electrolyseurs de la Vapeur d'Eau à haute température - ANR-18-CE05-0036
dc.language.isoen
dc.publisherElsevier
dc.subject.enLanthanide nickelates
dc.subject.enSOFC cathode
dc.subject.enSOEC anode
dc.subject.enAgeing
dc.subject.enDegradation 2
dc.title.enElectrochemical ageing study of mixed lanthanum/praseodymium nickelates La2-PrNiO4+δ as oxygen electrodes for solid oxide fuel or electrolysis cells
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jechem.2019.10.012
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Energy Chemistry
bordeaux.page62-70
bordeaux.volume46
bordeaux.peerReviewedoui
hal.identifierhal-02354352
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02354352v1
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