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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorRAVEZ, Jean
dc.date.created1997
dc.date.issued1997
dc.identifier.issn1155-4320
dc.description.abstractEnThe ferroelectric fluorides belong to six families of type (NH4)2BeF4, BaMnF4, SrAlF5, Na2MgAlF7, K3Fe5F15 or Pb5Cr3F19. The oxyfluorides can be separated in two groups: i) the true oxyfluorides with a relatively high F/O value (K3MoO3F3, Na5W3O9F5, Pb5W3O9F10, Bi2TiO4F2, ...); ii) the compositions derived from ferroelectric oxides (perovskite, tetragonal tungsten bronze, pyrochlore, LiTaO3, ...) characterized by a continuous F-O substitution. The phase transitions and the physical properties are discussed. The origin of the spontaneous polarization is described structurally. The variations of the Curie temperature with the type of substitution are related to chemical bonding. The potential interest of these materials for applications is briefly given.
dc.language.isoen
dc.publisherEDP Sciences
dc.subject.enFerroelectrics
dc.subject.enOxyfluoride
dc.subject.enFluoride
dc.subject.enInorganic compounds
dc.title.enThe Inorganic Fluoride and Oxyfluoride Ferroelectrics
dc.typeArticle de revue
dc.identifier.doi10.1051/jp3:1997175
dc.subject.halPhysique [physics]/Articles anciens
bordeaux.journalJournal de Physique III
bordeaux.page1129-1144
bordeaux.volume7
bordeaux.issue6
bordeaux.peerReviewedoui
hal.identifierjpa-00249637
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//jpa-00249637v1
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