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Spin crossover properties of the [Fe(PM-BiA)2(NCS)2] complex - phases I and II
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LÉTARD, Jean-François | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHASTANET, Guillaume | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | NGUYEN, Olivier | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | MARCÉN, Silvia | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | MARCHIVIE, Mathieu | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GUIONNEAU, Philippe | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHASSEAU, Daniel | |
hal.structure.identifier | Insitut für Anorganische und Analytische Chemie | |
dc.contributor.author | GUTLICH, Philipp | |
dc.date.issued | 2003 | |
dc.identifier.issn | 0026-9247 | |
dc.description.abstractEn | In the present review, we reexamine the photomagnetic properties of the [Fe(PM-BiA)2(NCS)2], cis-bis(thiocyanato)-bis[(N-2'-pyridylmethylene)-4-(aminobiphenyl)]iron(II), compound which exhibits, depending on the synthetic method, an exceptionally abrupt spin transition (phase I) with a very narrow hysteresis (T1/2O = 168 K and T1/2N = 173 K) or a gradual spin conversion (phase II) occurring at 190 K. In both cases, light irradiation in the tail of the 1MLCT-LS absorption band, at 830 nm, results in the population of the high-spin state according to the light-induced excited spin-state trapping (LIESST) effect. The capacity of a compound to retain the light-induced HS information, estimated through the T(LIESST) experiment, is determined for both phases. Interestingly, the shape of the T(LIESST) curve is more gradual for the phase II than for the phase I and the T(LIESST) value is found considerably lower in the case of the phase II. The kinetics parameters involved in the photoinduced high-spinMlow-spin relaxation process are estimated for both phases. From these data, the experimental T(LIESST) curves are simulated and the particular influence of the cooperativity as well as of the parameters involved in the thermally activated and tunneling regions are discussed. The Light-Induced Thermal Hysteresis (LITH), originally described for the strongly cooperative phase I, is also reinvestigated. The quasi-static LITH loop is determined by recording the photostationary points in the warming and cooling branches. | |
dc.language.iso | en | |
dc.publisher | Springer Verlag | |
dc.subject.en | Kinetic relaxation | |
dc.subject.en | Spin crossover | |
dc.subject.en | Iron(II) | |
dc.subject.en | Photomagnetism | |
dc.subject.en | Kinetic relaxation. | |
dc.title.en | Spin crossover properties of the [Fe(PM-BiA)2(NCS)2] complex - phases I and II | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1007/s00706-002-0537-0 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Chemical Monthly = Monatshefte für Chemie | |
bordeaux.page | 165-182 | |
bordeaux.volume | 134 | |
bordeaux.issue | 2 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00258375 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00258375v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Monthly%20=%20Monatshefte%20f%C3%BCr%20Chemie&rft.date=2003&rft.volume=134&rft.issue=2&rft.spage=165-182&rft.epage=165-182&rft.eissn=0026-9247&rft.issn=0026-9247&rft.au=L%C3%89TARD,%20Jean-Fran%C3%A7ois&CHASTANET,%20Guillaume&NGUYEN,%20Olivier&MARC%C3%89N,%20Silvia&MARCHIVIE,%20Mathieu&rft.genre=article |
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