Afficher la notice abrégée

Metal-to-ligand charge transfer chirality sensing of d-glucose assisted with GOX-based enzymatic reaction

hal.structure.identifierHubei University
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierSchool of Materials Science and Engineering and School of Computer Science and Information Engineering
hal.structure.identifierDepartment of Electrical and Electronic Engineering
dc.contributor.authorHAO, Junjie
hal.structure.identifierHubei University
hal.structure.identifierSchool of Materials Science and Engineering and School of Computer Science and Information Engineering
dc.contributor.authorLI, Yiwen
hal.structure.identifierDepartment of Developmental Cell Biology Key Laboratory of Cell Biology Ministry of Public Health and Key Laboratory of Medical Cell Biology
dc.contributor.authorXU, Xiaoqian
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorZHAO, Fenghuan
hal.structure.identifierHubei University
hal.structure.identifierSchool of Materials Science and Engineering and School of Computer Science and Information Engineering
dc.contributor.authorPAN, Ruikun
hal.structure.identifierCollege of Physics and Optoelectronic Engineering
dc.contributor.authorLI, Junzi
hal.structure.identifierDepartment of Electrical and Electronic Engineering
dc.contributor.authorLIU, Haochen
hal.structure.identifierDepartment of Electrical and Electronic Engineering
dc.contributor.authorWANG, Kai
hal.structure.identifierShenzhen Institute of Artificial Intelligence and Robotics for Society [AIRS]
dc.contributor.authorLI, Jiagen
hal.structure.identifierShenzhen Institute of Artificial Intelligence and Robotics for Society [AIRS]
dc.contributor.authorZHU, Xi
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDELVILLE, Marie-Hélène
hal.structure.identifierHubei University
hal.structure.identifierSchool of Materials Science and Engineering and School of Computer Science and Information Engineering
dc.contributor.authorZHANG, Ming
hal.structure.identifierCollege of Physics and Optoelectronic Engineering
dc.contributor.authorHE, Tingchao
hal.structure.identifierHubei University
hal.structure.identifierSchool of Materials Science and Engineering and School of Computer Science and Information Engineering
dc.contributor.authorCHENG, Jiaji
dc.date.issued2020
dc.identifier.issn2365-709X
dc.description.abstractEnChiral transition metal oxides nanoparticles (NPs) with tunable optical properties are widely accepted as promising toolbox for chiral recognition, stereoselective synthesis, and chiroptical devices. Herein, chirality‐based strategy is presented for discrimination of d ‐glucose from its enantiomer through a cooperative synergy between chiral cysteine capped MoO2 NPs and the glucose oxidase nanosystem. The valence‐state‐dependent chirality induced by metal‐ligand charge transfer effect is found to be ultrasensitive to its redox environment such as the presence of hydrogen peroxide, which is a key indicator of the stereoselective enzymatic reaction between glucose oxidase and d ‐glucose. With this know‐how, glucose enantiomers can be precisely quantified with a limit of detection of 0.446 µm . Such a chiral bio‐nanosystem would be an ideal platform for a rational design of new types of biosensors, photocatalysts, and chirality‐based nanodevices.
dc.language.isoen
dc.publisherWiley
dc.title.enMetal-to-ligand charge transfer chirality sensing of d-glucose assisted with GOX-based enzymatic reaction
dc.typeArticle de revue
dc.identifier.doi10.1002/admt.202000138
dc.subject.halChimie/Matériaux
bordeaux.journalAdvanced Materials Technologies
bordeaux.page2000138
bordeaux.volume5
bordeaux.issue7
bordeaux.peerReviewedoui
hal.identifierhal-02899871
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02899871v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Advanced%20Materials%20Technologies&rft.date=2020&rft.volume=5&rft.issue=7&rft.spage=2000138&rft.epage=2000138&rft.eissn=2365-709X&rft.issn=2365-709X&rft.au=HAO,%20Junjie&LI,%20Yiwen&XU,%20Xiaoqian&ZHAO,%20Fenghuan&PAN,%20Ruikun&rft.genre=article


Fichier(s) constituant ce document

FichiersTailleFormatVue

Il n'y a pas de fichiers associés à ce document.

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée