Mostrar el registro sencillo del ítem

Solution-State Spin Crossover in a Family of [Fe(L)2(CH3CN)2](BF4)2 Complexes

hal.structure.identifierMacDiarmid Institute for Advanced Materials and Nanotechnology
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorWILSON, Benjamin
hal.structure.identifierMacDiarmid Institute for Advanced Materials and Nanotechnology
dc.contributor.authorSCOTT, Hayley
hal.structure.identifierMacDiarmid Institute for Advanced Materials and Nanotechnology
dc.contributor.authorARCHER, Rosanna
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierCentre de Recherche Paul Pascal [CRPP]
dc.contributor.authorCLÉRAC, Rodolphe
hal.structure.identifierMacDiarmid Institute for Advanced Materials and Nanotechnology
dc.contributor.authorKRUGER, Paul
dc.date.issued2019-06
dc.identifier.issn2312-7481
dc.description.abstractEnWe report herein on five new Fe(II) complexes of general formula [Fe(L)2(NCCH3)2](BF4)2xCH3CN (L = substituted 2-pyridylimine-based ligands). The influence of proximally located electron withdrawing groups (e.g., NO2, CN, CF3, Cl, Br) bound to coordinated pyridylimine ligands has been studied for the effect on spin crossover in their Fe(II) complexes.Variable-temperature UV-visible spectroscopic studies performed on complexes with more strongly electronegative ligand substituents revealed spin crossover (SCO) in the solution, and thermodynamic parameters associated with the spin crossover were estimated.
dc.language.isoen
dc.publisherMDPI
dc.subject.enFe(II)
dc.title.enSolution-State Spin Crossover in a Family of [Fe(L)2(CH3CN)2](BF4)2 Complexes
dc.typeArticle de revue
dc.identifier.doi10.3390/magnetochemistry5020022
dc.subject.halChimie/Matériaux
bordeaux.journalMagnetochemistry
bordeaux.page22 (13 p.)
bordeaux.volume5
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-02171591
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02171591v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Magnetochemistry&rft.date=2019-06&rft.volume=5&rft.issue=2&rft.spage=22%20(13%20p.)&rft.epage=22%20(13%20p.)&rft.eissn=2312-7481&rft.issn=2312-7481&rft.au=WILSON,%20Benjamin&SCOTT,%20Hayley&ARCHER,%20Rosanna&MATHONI%C3%88RE,%20Corine&CL%C3%89RAC,%20Rodolphe&rft.genre=article


Archivos en el ítem

ArchivosTamañoFormatoVer

No hay archivos asociados a este ítem.

Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem