Effect of metal dilution on the light-induced spin transition in [FexZn1-x(phen)2(NCS)2] (phen = 1,10-phenanthroline)
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | BALDÉ, Cherif | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DESPLANCHES, Cédric | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | WATTIAUX, Alain | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| hal.structure.identifier | Insitut für Anorganische und Analytische Chemie | |
| dc.contributor.author | GÜTLICH, Philipp | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 1477-9226 | |
| dc.description.abstractEn | The thermal and light-induced spin transitions in [FexZn1-x(phen)2(NCS)2] (phen = 1,10-phenantholine) have been investigated by magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. These complexes display a thermal spin transition and undergo the light-induced excited spin state trapping (LIESST) effect at low temperatures. For each compound, the thermal spin transition temperature, T1/2, and the relaxation temperature of the photo-induced high-spin state, T(LIESST), have been systematically determined. It appears that T1/2 decreases with the metal dilution while T(LIESST) remains unchanged. This behaviour is discussed on the basis of the kinetic study governing the photo-induced back conversion. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | LIESST | |
| dc.subject.en | Magnetic susceptibility | |
| dc.subject.en | Photomagnetism | |
| dc.subject.en | Diffuse reflectivity measurements | |
| dc.subject.en | Metal | |
| dc.subject.en | Chemical compounds | |
| dc.title.en | Effect of metal dilution on the light-induced spin transition in [FexZn1-x(phen)2(NCS)2] (phen = 1,10-phenanthroline) | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/b800248g | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Dalton Transactions | |
| bordeaux.page | 2702-2707 | |
| bordeaux.issue | 20 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00293412 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00293412v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Dalton%20Transactions&rft.date=2008&rft.issue=20&rft.spage=2702-2707&rft.epage=2702-2707&rft.eissn=1477-9226&rft.issn=1477-9226&rft.au=BALD%C3%89,%20Cherif&DESPLANCHES,%20C%C3%A9dric&WATTIAUX,%20Alain&GUIONNEAU,%20Philippe&G%C3%9CTLICH,%20Philipp&rft.genre=article |
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