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Unprecedented reverse volume expansion in spin‐transition crystals

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUO, Wenbin
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDARO, Nathalie
hal.structure.identifierCristallographie, Résonance Magnétique et Modélisations [CRM2]
dc.contributor.authorPILLET, Sébastien
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMARCHIVIE, Mathieu
hal.structure.identifierCristallographie, Résonance Magnétique et Modélisations [CRM2]
dc.contributor.authorBENDEIF, El-Eulmi
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorTAILLEUR, Elodie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierMaterials and Textiles Technology
dc.contributor.authorCHAINOK, Kittipong
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDENUX, Dominique
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASTANET, Guillaume
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
dc.date.issued2020
dc.identifier.issn0947-6539
dc.description.abstractEnThis paper gives an overview of the research carried out on lithium and sodium layered materials as positive electrodes of lithium (sodium)‐ion batteries. It focuses on the solid‐state chemistry contribution to discover new materials and to optimize the properties versus the requirements imposed by the applications. Among, all material structures, which are considered, the layered ones (lithium based), are the best candidates for high energy density batteries for mobile applications. Recently, the homologous Na materials, which have lower energy, are considered for stationary applications due to their low price. Starting for LiMO2 materials or NaxMO2 (0.5 < x < 1), many substituted phases, obtained by high‐temperature solid‐state chemistry, have allowed stabilizing the layered structure in large composition domains to increase the specific capacity, which is directly related to the number of exchanged electrons during the cycling process.
dc.description.sponsorshipIsite LUE - ANR-15-IDEX-0004
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enUnprecedented reverse volume expansion in spin‐transition crystals
dc.typeArticle de revue
dc.identifier.doi10.1002/chem.202001821
dc.subject.halChimie/Matériaux
bordeaux.journalChemistry - A European Journal
bordeaux.page12927-12930
bordeaux.volume26
bordeaux.issue57
bordeaux.peerReviewedoui
hal.identifierhal-02945219
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02945219v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Chemistry%20-%20A%20European%20Journal&amp;rft.date=2020&amp;rft.volume=26&amp;rft.issue=57&amp;rft.spage=12927-12930&amp;rft.epage=12927-12930&amp;rft.eissn=0947-6539&amp;rft.issn=0947-6539&amp;rft.au=GUO,%20Wenbin&amp;DARO,%20Nathalie&amp;PILLET,%20S%C3%A9bastien&amp;MARCHIVIE,%20Mathieu&amp;BENDEIF,%20El-Eulmi&amp;rft.genre=article


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