Radiation-induced synthesis of gold nanoparticles within lamellar Phases. Formation of aligned colloidal gold by radiolysis
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
dc.contributor.author | MEYRE, Marie-Edith | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | TRÉGUER-DELAPIERRE, Mona | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
dc.contributor.author | FAURE, Chrystel | |
dc.date.issued | 2008 | |
dc.identifier.issn | 0743-7463 | |
dc.description.abstractEn | A sheared lamellar phase has been used as a nanoreactor for the synthesis of gold nanoparticles by radiolysis and by a photochemical approach. A gold salt solution (KAuCl4, 10-2 M) is introduced into the aqueous compartments between the lipid-based bilayers. Gold nanoparticles grow within the lamellar phase as shown by TEM analysis and X-ray diffraction, limiting the particle size. Homodisperse, 2.4- and 5.9-nm-sized, spherical nanoparticles are produced by irradiation and UV irradiation, respectively. When produced by radiolysis, they are perfectly aligned along the lamellae. Their UV-vis spectra display a maximum at 565 nm suggesting that nanoparticles are coupled by dipole-dipole interactions within the lamellar phase. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.subject.en | Gold | |
dc.subject.en | Chemical synthesis | |
dc.subject.en | Nanoparticles | |
dc.subject.en | Colloids | |
dc.title.en | Radiation-induced synthesis of gold nanoparticles within lamellar Phases. Formation of aligned colloidal gold by radiolysis | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/la703650d | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Langmuir | |
bordeaux.page | 4421-4425 | |
bordeaux.volume | 24 | |
bordeaux.issue | 9 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00300268 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00300268v1 | |
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