Thermally-stable high energy storage performances and large electrocaloric effect over a broad temperature span in lead-free BCZT ceramic
hal.structure.identifier | Université Cadi Ayyad [Marrakech] [UCA] | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | HANANI, Zouhair | |
hal.structure.identifier | Université Cadi Ayyad [Marrakech] [UCA] | |
dc.contributor.author | MERSELMIZ, Soukaina | |
hal.structure.identifier | Université Cadi Ayyad [Marrakech] [UCA] | |
dc.contributor.author | MEZZANE, Daoud | |
hal.structure.identifier | Université Cadi Ayyad [Marrakech] [UCA] | |
dc.contributor.author | AMJOUD, M'Barek | |
hal.structure.identifier | Jozef Stefan Institute [Ljubljana] [IJS] | |
dc.contributor.author | BRADEŠKO, Andraž | |
hal.structure.identifier | Jozef Stefan Institute [Ljubljana] [IJS] | |
dc.contributor.author | ROŽIČ, Brigita | |
hal.structure.identifier | Université Cadi Ayyad [Marrakech] [UCA] | |
hal.structure.identifier | Université Mohammed VI Polytechnique = Mohammed VI Polytechnic University [Ben Guerir] [UM6P] | |
dc.contributor.author | LAHCINI, Mohammed | |
hal.structure.identifier | Laboratoire de Physique de la Matière Condensée - UR UPJV 2081 [LPMC] | |
dc.contributor.author | EL MARSSI, Mimoun | |
hal.structure.identifier | I.N. Frantsevich Institute for Problems of Materials Science of NAS of Ukraine [IPMS] | |
dc.contributor.author | RAGULYA, Andrey | |
hal.structure.identifier | Laboratoire de Physique de la Matière Condensée - UR UPJV 2081 [LPMC] | |
hal.structure.identifier | Physics Faculty | |
dc.contributor.author | LUK'YANCHUK, Igor A. | |
hal.structure.identifier | Jozef Stefan Institute [Ljubljana] [IJS] | |
dc.contributor.author | KUTNJAK, Zdravko | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GOUNÉ, Mohamed | |
dc.date.issued | 2020-08-20 | |
dc.description.abstractEn | Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT) relaxor ferroelectric ceramics exhibit enhanced energy storage and electrocaloric performances due to their excellent dielectric and ferroelectric properties. In this study, the temperature-dependence of the structural and dielectric properties, as well as the field and temperature-dependence of the energy storage and the electrocaloric properties in BCZT ceramics elaborated at low-temperature hydrothermal processing are investigated. X-ray diffraction and Raman spectroscopy results confirmed the ferroelectric–paraelectric phase transition in the BCZT ceramic. At room temperature and 1 kHz, the dielectric constant and dielectric loss reached 5000 and 0.029, respectively. The BCZT ceramic showed a large recovered energy density (Wrec) of 414.1 mJ cm−3 at 380 K, with an energy efficiency of 78.6%, and high thermal-stability of Wrec of 3.9% in the temperature range of 340–400 K. The electrocaloric effect in BCZT was explored via an indirect approach following the Maxwell relation at 60 kV cm−1. The significant electrocaloric temperature change of 1.479 K at 367 K, a broad temperature span of 87 K, an enhanced refrigerant capacity of 140.33 J kg−1, and a high coefficient of performance of 6.12 obtained at 60 kV cm−1 make BCZT ceramics potentially useful coolant materials in the development of future eco-friendly solid-state refrigeration technology. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.title.en | Thermally-stable high energy storage performances and large electrocaloric effect over a broad temperature span in lead-free BCZT ceramic | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/D0RA06116F | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | RSC Advances | |
bordeaux.page | 30746-30755 | |
bordeaux.volume | 10 | |
bordeaux.issue | 51 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-02981577 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-02981577v1 | |
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