First example of photomagnetic effects in ionic pairs [Ni(bipy)3]2[Mo(CN)8] · 12H2O
| hal.structure.identifier | Faculty of Chemistry | |
| dc.contributor.author | KORZENIAK, Tomasz | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | KAIBA, Abdellah | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| hal.structure.identifier | Faculty of Chemistry | |
| dc.contributor.author | KOZIEL, Marcin | |
| hal.structure.identifier | Faculty of Chemistry | |
| dc.contributor.author | SIEKLUCKA, Barbara | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 0020-1693 | |
| dc.description.abstractEn | Ionic triads formed by [NiII(bipy)3]2+ (bipy = 2,20-bipyridyl) and diamagnetic [MIV(CN)8]4 (M = Mo and W) were prepared and structurally characterized. The two compounds are isostructural and their structure consists of a three-dimensional hydrogen-bonded framework where cation–anion interactions occur through short contacts M–CN H–C(bipy). Before irradiation, the Mo analogue behaves as paramagnet with small intermolecular interactions between the [NiII(bipy)3]2+ cations. Upon irradiation with visible light, it exhibits a reversible photomagnetic effect, which is interpreted in terms of the formation of paramagnetic [MoV(CN)8]3 and [NiII(bipy)2(bipy )]+ due to the outer-sphere electron transfer. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Coordination compounds | |
| dc.subject.en | Octacyanomolybdate | |
| dc.subject.en | Electron transfer | |
| dc.subject.en | Magnetism | |
| dc.subject.en | Photomagnetism | |
| dc.title.en | First example of photomagnetic effects in ionic pairs [Ni(bipy)3]2[Mo(CN)8] · 12H2O | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.ica.2008.03.001 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Inorganica Chimica Acta | |
| bordeaux.page | 3500-3504 | |
| bordeaux.volume | 361 | |
| bordeaux.issue | 12-13 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00324030 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00324030v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganica%20Chimica%20Acta&rft.date=2008&rft.volume=361&rft.issue=12-13&rft.spage=3500-3504&rft.epage=3500-3504&rft.eissn=0020-1693&rft.issn=0020-1693&rft.au=KORZENIAK,%20Tomasz&MATHONI%C3%88RE,%20Corine&KAIBA,%20Abdellah&GUIONNEAU,%20Philippe&KOZIEL,%20Marcin&rft.genre=article |
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