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Second-harmonic generation in sodium and niobium borophosphate glasses after poling under field-assisted silver ions anodic injection

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierDepartment of Material Science
dc.contributor.authorMALAKHO, Artem
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFARGIN, Evelyne
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDELESTRE, Aurélien
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorANDRÉ, Clément
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARDINAL, Thierry
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLAHAYE, Michel
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorRODRIGUEZ, Vincent
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorCOUZI, Michel
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorADAMIETZ, Frédéric
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorCANIONI, Lionel
hal.structure.identifierCentre de physique moléculaire optique et hertzienne [CPMOH]
dc.contributor.authorROYON, Arnaud
dc.date.issued2008
dc.identifier.issn0021-8979
dc.description.abstractEnMonovalent silver ions, resulting from a thin silver layer initially deposited at the anode surface, have been introduced using the field-assisted ion-exchange technique in sodium niobium borophosphate glasses. A reproducible susceptibility chi(2) could be gained after this poling treatment, although a drop in the nonlinearity is observed due to the introduction of silver ions. From energy dispersive x-ray spectroscopy, it has been found that the nonlinear layer is characterized by a strong migration of sodium ions 4 µm deep inside the anode side, which have been partially replaced by silver ions. These results indicate a complex space-charge-migration process during the poling treatment, which is involved in the decrease in the mean second-harmonic generation signal.
dc.language.isoen
dc.publisherAmerican Institute of Physics
dc.subject.enOptical glass
dc.subject.enOptical harmonic generation
dc.subject.enSilver
dc.subject.enDielectric polarisation
dc.subject.enIon exchange
dc.subject.enNonlinear optical susceptibility
dc.title.enSecond-harmonic generation in sodium and niobium borophosphate glasses after poling under field-assisted silver ions anodic injection
dc.typeArticle de revue
dc.identifier.doi10.1063/1.2973156
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Applied Physics
bordeaux.page053114 (4 p.)
bordeaux.volume104
bordeaux.issue5
bordeaux.peerReviewedoui
hal.identifierhal-00326042
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00326042v1
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