Cyanide-bridged tetradecanuclear RuII3MII11 clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6−: structural and photophysical properties
| hal.structure.identifier | Departamento de Química Inorgánica | |
| dc.contributor.author | HERRERA, Juan Manuel | |
| hal.structure.identifier | Departamento de Química Inorgánica | |
| dc.contributor.author | COLACIO, Enrique | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Laboratorio de Estudios Cristalográficos | |
| dc.contributor.author | CHOQUESILLO-LAZARTE, Duane | |
| hal.structure.identifier | Department of Chemistry [Sheffield] | |
| dc.contributor.author | WARD, Michael D. | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 1359-7345 | |
| dc.description.abstractEn | Reaction of the anionic cyanometallate chromophore [{Ru(CN)4}3(3-HAT)]6− with [MII(tren)]2+ complexes (M = ZnII, CuII) provides discrete tetradecanuclear clusters of formula [{MII(tren)(-CN)}11{Ru3(HAT)(CN)}]16+; the weak luminescence of the Ru3 chromophore is substantially enhanced in the presence of ZnII ions, whereas it is completely quenched when CuII centers are present. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | Zinc | |
| dc.subject.en | Copper | |
| dc.subject.en | Ruthenium | |
| dc.subject.en | Luminescence | |
| dc.subject.en | Chromophore | |
| dc.subject.en | Cyanometallate | |
| dc.title.en | Cyanide-bridged tetradecanuclear RuII3MII11 clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6−: structural and photophysical properties | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/b807364c | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Chemical Communications | |
| bordeaux.page | 4460-4462 | |
| bordeaux.issue | 37 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00326973 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00326973v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Communications&rft.date=2008&rft.issue=37&rft.spage=4460-4462&rft.epage=4460-4462&rft.eissn=1359-7345&rft.issn=1359-7345&rft.au=HERRERA,%20Juan%20Manuel&COLACIO,%20Enrique&MATHONI%C3%88RE,%20Corine&CHOQUESILLO-LAZARTE,%20Duane&WARD,%20Michael%20D.&rft.genre=article |
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