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Rational direct synthesis of [Fe(Htrz)2(trz)](BF4) polymorphs: temperature and concentration effects

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPALLUEL, Marlène
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorEL KHOURY, Liza
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDARO, Nathalie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBUFFIERE, Sonia
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorJOSSE, Michaël
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMARCHIVIE, Mathieu
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASTANET, Guillaume
dc.date.issued2021
dc.identifier.issn2052-1553
dc.description.abstractEnThe [Fe(Htrz)2trz](BF4) compound is probably the most studied in the spin crossover (SCO) community since it exhibits switching properties with a large temperature range of memory effect, just above room temperature. We present in this paper a detailed study of the influence of the synthetic parameters on the polymorphism of this compound. While the crystal structure of polymorph I is already known, we report the crystal structure of polymorph II and discuss the differences to allow further studies to discriminate between the two. This was achieved through the resolution of the crystal structure of the [Fe(Htrz)2(trz)](PF6) analogue. This study allows us to draw a phase diagram and to discuss the effect of the reaction conditions on the formation of polymorphs, the size of the particles and their properties.
dc.description.sponsorshipNanomatériaux hybrides pour une commutation photo-thermique contrôlée - ANR-17-CE09-0010
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enRational direct synthesis of [Fe(Htrz)2(trz)](BF4) polymorphs: temperature and concentration effects
dc.typeArticle de revue
dc.identifier.doi10.1039/D1QI00482D
dc.subject.halChimie/Chimie de coordination
dc.subject.halChimie/Cristallographie
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry Frontiers
bordeaux.page3697-3706
bordeaux.volume8
bordeaux.issue15
bordeaux.peerReviewedoui
hal.identifierhal-03304287
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03304287v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry%20Frontiers&rft.date=2021&rft.volume=8&rft.issue=15&rft.spage=3697-3706&rft.epage=3697-3706&rft.eissn=2052-1553&rft.issn=2052-1553&rft.au=PALLUEL,%20Marl%C3%A8ne&EL%20KHOURY,%20Liza&DARO,%20Nathalie&BUFFIERE,%20Sonia&JOSSE,%20Micha%C3%ABl&rft.genre=article


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