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Understanding the two-step spin-transition phenomenon in iron(II) 1D chain materials

hal.structure.identifierSchool of Chemistry
dc.contributor.authorNEVILLE, Suzanne M.
hal.structure.identifierSchool of Chemistry
dc.contributor.authorLEITA, Benjamin A.
hal.structure.identifierSchool of Chemistry
hal.structure.identifierMaterial Science Division [ANL] [MSD]
dc.contributor.authorHALDER, Gregory J.
hal.structure.identifierSchool of Chemistry
dc.contributor.authorKEPERT, Cameron J.
hal.structure.identifierSchool of Chemistry
dc.contributor.authorMOUBARAKI, Boujemaa
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierSchool of Chemistry
dc.contributor.authorMURRAY, Keith S.
dc.date.issued2008
dc.identifier.issn0947-6539
dc.description.abstractEnThree analogous one dimensional (ID) polymeric iron(II) spin crossover (SCO) materials containing the new ligand 4,6-bis(2′,2″-pyridyl) pyrazine (bdpp) have been comprehensively characterised magnetically (thermal and light-induced) and structurally. Within this series are two polymorphs of the formula [Fe(NCS)2:(bdpp)], 1 and 2a, which differ magnetically in that phase 1 undergoes a full two-step SCO (T1/2(1) = 135 K and T1/2(2) = 90K) whereas phase 2a remains high spin (HS) over all temperatures. The central distinction between these two materials lies in the presence of intermolecular π-π interactions generated by the crystal packing in 1, which are absent in 2a. The isostructural selenocyanate analogue of 2a, [Fe(NCSe)2(bdpp)], 2b, undergoes a full two-step SCO (T 1/2(1)) = 200 K and T1/2(2) =125 K). Structural analyses of 1 and 2b at a range of temperatures provide deep insight into their two-step SCO nature. Structural analysis of 1 at 25 K (1LS-LS), 123 K (1 LS-HS) and 250 K (1HS-HS) reveals two distinct iron(II) centres at each temperature, with ordered, alternating HS and LS (low spin) sites at the intermediate plateau (IP) temperatures. In contrast, structural analysis of 2b at 90 K (2bLS), 150 K (2bLS/HS) and 250 K (2bHS) reveals one unique iron(II) centre at each temperature with an "averaged" LS/HS character at the IP temperature. Weak planes of diffuse scattering in the single-crystal X-ray diffraction patterns were observed for this phase at 90 and 150 K, indicating that ID long range ordering of alternating HS/LS iron(II) centres occurs along the ID coordination chains, but that there is no correlation between chains. The lack of observable diffuse scattering at 250 K suggests that the onset of the 1D structural ordering in the chain direction corresponds to the first step of the SCO and that this structural transition is electronically driven. The photomagnetic properties of both 1 and 2b have been investigated and show ≈62 and 53 % photo-excitation of a HS metastable state at low temperatures and T(LIESST) values of 55 and 49 K, respectively. Relaxation studies on the HS fraction in 2b fitted well to a stretched exponential model with kinetic parameters indicative of weak cooperativity.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.en1D chain
dc.subject.enChain structures
dc.subject.enIron
dc.subject.enMagnetic properties
dc.subject.enSpin crossover
dc.title.enUnderstanding the two-step spin-transition phenomenon in iron(II) 1D chain materials
dc.typeArticle de revue
dc.identifier.doi10.1002/chem.200800886
dc.subject.halChimie/Matériaux
bordeaux.journalChemistry - A European Journal
bordeaux.page10123-10133
bordeaux.volume14
bordeaux.issue32
bordeaux.peerReviewedoui
hal.identifierhal-00339976
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00339976v1
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